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Glycidyl methacrylate

Glycidyl methacrylate is a versatile epoxy-containing monomer used in a variety of polymer applications.
It can be copolymerized with other monomers to create materials with improved mechanical, thermal, and chemical properties.
Glycidyl methacrylate is commonly employed in the manufacture of coatings, adhesives, sealants, and composite materials.
Its epoxy functionality allows for crosslinking and grafting reactions, enhancing the performance of the final product.
Researchers studying glycidyl methacrylate can utilize PubCompare.ai to easily locate the best protocols and products from literature, preprints, and patents, optimizing their experiments and improving reproducibility and accuracy.

Most cited protocols related to «Glycidyl methacrylate»

Antibacterial NACP Nanocomposite Development

Cited 9 times

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Publication 2013

2-propylamine A-A-1 antibiotic Acetic Acid Anti-Bacterial Agents barium glass filler Biofilms bisphenol A camphorquinone Carbonate, Calcium Dental Health Services Dentsply dicalcium phosphate Electrostatics Esters Fungus, Filamentous gamma-methacryloxypropyltrimethoxysilane Ions Light Methacrylate Molar Paste Renamel Resins, Plant SNCA protein, human Triad resin triethylene glycoldimethacrylate

Synthesis of P(SSNa-co-GMA) Copolymers

Cited 5 times

The copolymers poly(sodium styrene sulfonate-co-glycidyl methacrylate) were synthesized through free radical polymerization in DMF/H₂O, using AIBN as initiator. The synthetic procedure is illustrated in Scheme 1. The copolymer is denoted as P(SSNax-co-GMA(1 − x)), where x is the mol fraction of SSNa units and (1 − x) is the mol fraction of GMA units, respectively, in the copolymer, as determined by ¹H NMR characterization in D₂O. Briefly, the desired quantity of the two monomers (total monomer concentration 1 M) was dissolved in the appropriate solvent, the solution was degassed, and the initiator AIBN (0.02 mol % over the total monomer concentration) was added. The reaction was left to proceed overnight under vigorous stirring in an Ar atmosphere in an oil bath set at 80 °C. After cooling down to room temperature, the copolymers were recovered by precipitation in acetone, filtered and dried in a vacuum oven at 60 °C for 24 h.
A representative ¹H NMR spectrum of the copolymer P(SSNa-co-GMA0.2) with a GMA content 20%, is illustrated in Figure 1, where the characteristic peaks of SSNa and GMA are observed. More specifically, the peaks at 6.0–8.0 ppm are assigned to the aromatic protons of SSNa. As far as GMA is concerned, signal originating from the methylene bonded to the ester oxygen was observed at 3.3 ppm (h type protons), the methine proton of the oxirane ring was observed at 2.9 ppm (f type protons), while two protons for the methylene of the ring were observed at 2.7–2.8 ppm (g type protons). The peak at 4.7 ppm is attributed to the deuterated water.

Lainioti G.C., Bounos G., Voyiatzis G.A, & Kallitsis J.K. (2016). Enhanced Water Vapor Transmission through Porous Membranes Based on Melt Blending of Polystyrene Sulfonate with Polyethylene Copolymers and Their CNT Nanocomposites. Polymers, 8(5), 190.

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Publication 2016

1H NMR Acetone Alkanesulfonates Atmosphere azobis(isobutyronitrile) Bath carbene Esters Free Radicals Oxide, Ethylene Oxygen Poly A Polymerization Protons sodium methacrylate Solvents Styrene Vacuum

Racial Disparities in EDCs and Women's Health

Cited 5 times

To conduct a literature review of racial/ethnic disparities in environmental chemicals and the effects on women’s health outcomes in the U.S., we searched all English articles in PubMed and EMBASE from the inception of all databases to Jan 15, 2016. We pre-specified four major EDCs (phthalates, BPA, parabens and PBDEs) and specific women’s reproductive health outcomes (i.e. puberty, fibroids, pregnancy, and pregnancy complications). In article searching for chemical exposures from Pubmed, we combined the Medical Subject Headings (MeSH) terms and key words as follows: “phthalic acids,” “bisphenol A-glycidyl methacrylate,” “parabens,” or “halogenated diphenyl ethers,” as MeSH terms, and phthalic acid, phthalate, bisphenol A, methylparaben, butylparaben, propylparaben, polybrominated diphenyl ether, and organobromine compound as specific key words in texts.
For women’s health outcomes, the MeSH terms included “puberty,” “puberty, delayed,” “puberty, precocious,” “pregnancy,” “infertility, female,” “ovarian reserve,” “ovarian follicle,” “pregnancy complications,” “premature birth,” and “leiomyoma,” key words included menarche, thelarche, breast development, antral follicle count, preeclampsia, gestational diabetes and preterm.
Similarly, in our EMBASE search for chemical exposure, we combined Emtree terms and key words as follows: “phthalic acid derivative,” “phthalate,” “4,4 isopropylidenediphenol,” “4 hydroxybenzoic acid ester,” “propyl paraben,” “methyl paraben,” “ethyl paraben,” “butyl paraben,” “benzyl paraben,” and “polybrominated diphenyl ether” searched as Emtree terms; phthalate, BPA, paraben, polybrominated diphenyl ethers, and PBDE as key words in text.
For women’s health outcomes, we used all the Emtree terms including “puberty,” “delayed puberty,” “precocious puberty,” “adrenarche,” “breast development,” “pregnancy diabetes mellitus,” “preeclampsia,” “premature labor,” “pregnancy complication,” “pregnancy rate,” “uterus myoma,” and “leiomyoma. After excluding in vitro studies, animal studies, studies conducted outside of the U.S., as well as studies that did not assess the outcomes of interests, the searching strategies yielded a total of 612 articles in Pubmed and EMBASE.
We reviewed these articles and identified 46 discrete studies examining the association between environmental EDCs and women’s reproductive health outcomes among women living in the U.S. We also documented whether race-specific measures of association were reported in the main findings.

James-Todd T.M., Chiu Y.H, & Zota A.R. (2016). Racial/ethnic disparities in environmental endocrine disrupting chemicals and women’s reproductive health outcomes: epidemiological examples across the life course. Current epidemiology reports, 3(2), 161-180.

Publication 2016

4-hydroxybenzoic acid Adrenarche Animals benzylparaben bisphenol A Bisphenol A-Glycidyl Methacrylate Breast Brominated Diphenyl Ethers butylparaben Delayed Puberty Esters ethyl-p-hydroxybenzoate Females Gestational Diabetes Graafian Follicle Halogenated Diphenyl Ethers Menarche methylparaben Ovarian Follicle Ovarian Reserve Parabens phthalate phthalic acid Phthalic Acids Pre-Eclampsia Precocious Puberty Pregnancy Pregnancy Complications Pregnancy in Diabetics Premature Birth Premature Obstetric Labor propylparaben Puberty Sterility, Reproductive Uterine Fibroids Woman

Bioactive Adhesives with Nanoparticles for Dentin Bonding

Cited 5 times

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Publication 2015

2-hydroxyethyl methacrylate Acetic Acid Acetone Acids bisphenol A-glycidyl dimethacrylate Calcium, Dietary Carbonate, Calcium Dentin Dentsply dicalcium phosphate Electrostatics ethoxylated bis-phenol A dimethacrylate Glycerin Investigational New Drugs Ions itaconic acid Light Methacrylates Methylmethacrylate Molar Oligonucleotide Primers Oxides phosphine Powder Prime and Bond NT Resins, Plant Scotchbond SNCA protein, human Solvents

Nanopatterned PUA-PGMA Substratum Fabrication

Cited 4 times

A UV-curable poly(urethane acrylate) (PUA, Minutatek, Korea) mold was fabricated using capillary force lithography as published previously^{32 (link),33 (link),35 (link)} and was used as the nanopatterned template for the PUA-PGMA substratum (Figure 1a). To allow for epoxy functionalization of the fabricated nanopatterned substratum, 1% GMA weight/volume monomer (Sigma-Aldrich) was added to the liquid PUA precursor (Norland Optical Adhesive), sonicated for 1 h, and then hand mixed for 10 min. Solution was then degassed under a vacuum for 1 h to remove air bubbles. A glass coverslip (Ø18 mm, Fisher) was cleaned using isopropyl alcohol and brush coated with an adhesion promoter (Glass Primer, Minuta Tech) to allow for attachment of the polymer to the glass surface and air-dried. Twenty microliters of PUA-PGMA prepolymer was added to the coverslip and covered with the PUA template consisting of 800 nm wide and 500 nm deep parallel grooves and ridges. The PUA-PGMA prepolymer was spontaneously drawn into the nanofeatures of the PUA template via capillary force. The template–prepolymer–glass was cured under 365 nm UV light to initiate photopolymerization for 5 min. After polymerization, the PUA template was peeled off from the PUA-PGMA substratum using forceps and the substratum was UV-cured overnight to finalize polymerization.

Jiao A., Trosper N.E., Yang H.S., Kim J., Tsui J.H., Frankel S.D., Murry C.E, & Kim D.H. (2014). Thermoresponsive Nanofabricated Substratum for the Engineering of Three-Dimensional Tissues with Layer-by-Layer Architectural Control. ACS Nano, 8(5), 4430-4439.

Publication 2014

Capillaries Epoxy Resins Forceps Fungus, Filamentous Isopropyl Alcohol Oligonucleotide Primers Poly A Polymerization Polymers urethane acrylate Vacuum Vision

Most recents protocols related to «Glycidyl methacrylate»

Photocrosslinkable Hybrid Hydrogel Synthesis

The PVA-g-GMA (100 mmol of GMA) was dissolved in 10% v/v DMSO in deionized water to obtain a 10% (w/v) solution, stirred at 60 °C until a homogeneous solution was achieved. The 490 mM SF-g-GMA sponge was dissolved in deionized water at 50% w/v at room temperature. The mixed solutions of PVA-g-GMA and SF-g-GMA were thoroughly blended at different ratios of PVA-g-GMA to SF-g-GMA: 100/0, 75/25, 50/50, 25/75, and 0/100 (w/w of dry substances), followed by the addition of 0.3% (w/v) LAP. All gels were crosslinked with UV light (365 nm) for 10 min at an intensity of 6 mW/cm². Molds were utilized to create a 96-well plate with a well diameter of 6.72 mm.

Jeencham R., Sinna J., Ruksakulpiwat C., Tawonsawatruk T., Numpaisal P.O, & Ruksakulpiwat Y. (2024). Development of Biphasic Injectable Hydrogels for Meniscus Scaffold from Photocrosslinked Glycidyl Methacrylate-Modified Poly(Vinyl Alcohol)/Glycidyl Methacrylate-Modified Silk Fibroin. Polymers, 16(8), 1093.

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Publication 2024

Facile Synthesis of PVA-g-GMA

To obtain a 5% (w/v) PVA solution, PVA was dissolved in DMSO and stirred at 60 °C until it became transparent. The catalysts, 100 mmol of GMA and 0.17 mL of TEMED were then added and stirred at 60 °C for 6 h and cooled to room temperature. The PVA-g-GMA solution was allowed to air dry in a fume hood for 24 h at the ambient temperature. Then, the PVA-g-GMA was dried in a 60 °C hot air oven for 48 h before transferring to a vacuum oven at 45 °C for another 24 h.

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Publication 2024

Silk Fibroin-Grafted Glycidyl Methacrylate

Raw silk cocoons were cut into small pieces and degummed with 1% (w/v) Na₂CO₃ at a weight ratio of 1:50, boiled at 98 ± 2 °C for 30 min to remove sericin, and then washed with deionized water several times. Subsequently, the degummed silk was dried overnight at 60 °C in a hot air oven. We dissolved 10 grams of degummed silk in 100 mL of a mixture of CaCl₂/Ca(NO₃)₂/H₂O/EtOH (30/5/45/20 weight ratio) in a microwave (Samsung, MS23K3513AW, 800 W). In the grafting process, 0.490 mmol of GMA was added to the SF solution. The mixture was stirred at 300 rpm at 60 ± 2 °C for 1 h. The mixture was then dialyzed with deionized water using SnakeSkin dialysis tubing, with a molecular weight cutoff of 10 kDa for 3 days, and deionized water was replaced every 4 h to remove salts and non-reactions. After completion of the dialysis, the undissolved impurities were removed by centrifugation at 10,000 rpm at 4 °C for 20 min to eliminate silk aggregates as well as debris from the original cocoons. The mixture was frozen at −60 °C for 12 h and freeze-dried at −70 °C for 48 h. The freeze-dried SF-g-GMA was stored at room temperature in a desiccator until further use.

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Publication 2024

Silk Fibroin Hydrogel Fabrication

Raw silk cocoons from the mulberry silkworm Bombyx mori were acquired from the Queen Sirikit Department of Sericulture Center in Nakhon Ratchasima, Thailand. Poly(vinyl alcohol) (PVA) (Mw 13,000–23,000, 87–89% hydrolyzed), glycidyl methacrylate (GMA, 97%), N,N,N′,N′-tetramethylethylenediamine (TEMED, 99%), and lithium phenyl(2,4,6-trimethylbenzoyl)phosphinate (LAP) were procured from Sigma-Aldrich Corporation (St. Louis, MI, USA). Anhydrous sodium carbonate (Na₂CO₃) and absolute anhydrous ethanol (EtOH) were obtained from Carlo Erba Reagenti (Rodano, Milan, Italy), and anhydrous calcium chloride (CaCl₂) was sourced from ANaPURE (Auckland, New Zealand). Calcium nitrate 4-hydrate (Ca(NO₃)₂) was purchased from Kemaus. Dimethyl sulfoxide (DMSO) and acetone were procured from RCI Labscan Limited. Deuterium oxide (D₂O, 99.9%) and dimethyl sulfoxide-d₆ (DMSO-d₆, 99.9%) were sourced from Cambridge Isotope Laboratories. SnakeSkin dialysis tubing (molecular weight cut-off, 10 kDa) was obtained from Thermo Fisher Scientific Inc. (Waltham, MA, USA).

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Publication 2024

Synthesis of Methacrylated Gelatin Conjugate

GC was dissolved in 10 ml of distilled water (DW), and the pH was adjusted to 8.0 with 1 M NaOH to create a 2% (w/v) solution. This GC solution and glycidyl methacrylate were combined at a 0.75:1 molar ratio of glycidyl methacrylate to the amino groups in GC in DW. This mixture was allowed to react for up to 48 h. The reaction mixture was dialyzed using a molecular weight cutoff of 1 kDa of dialysis tubing using water for 2 d. The MGC solution was lyophilized to produce a white powder.

Seo H.S., Han J.H., Lim J., Bae G.H., Byun M.J., Wang C.P., Han J., Park J., Park H.H., Shin M., Park T.E., Kim T.H., Kim S.N., Park W, & Park C.G. (2024). Enhanced Postsurgical Cancer Treatment Using Methacrylated Glycol Chitosan Hydrogel for Sustained DNA/Doxorubicin Delivery and Immunotherapy. Biomaterials Research, 28, 0008.

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Publication 2024

Top products related to «Glycidyl methacrylate»

Glycidyl methacrylate by Merck Group

Sourced in United States, Germany, Italy, United Kingdom, Poland, Chile, France, Sao Tome and Principe

Glycidyl methacrylate is a chemical compound used in the production of various synthetic polymers. It is a bifunctional monomer, containing both an epoxide group and a methacrylate group, which allows it to participate in a range of polymerization reactions. The core function of glycidyl methacrylate is to serve as a building block in the synthesis of specialty polymers and copolymers, which find applications in diverse industries.

Azobisisobutyronitrile by Merck Group

Sourced in United States, Germany, United Kingdom, France, China, Poland, Italy

Azobisisobutyronitrile is a chemical compound used as a free radical initiator in various applications, particularly in the synthesis of polymers. It functions by generating free radicals that can initiate polymerization reactions.

Methanol by Merck Group

Sourced in Germany, United States, Italy, India, United Kingdom, China, France, Poland, Spain, Switzerland, Australia, Canada, Sao Tome and Principe, Brazil, Ireland, Japan, Belgium, Portugal, Singapore, Macao, Malaysia, Czechia, Mexico, Indonesia, Chile, Denmark, Sweden, Bulgaria, Netherlands, Finland, Hungary, Austria, Israel, Norway, Egypt, Argentina, Greece, Kenya, Thailand, Pakistan

Methanol is a clear, colorless, and flammable liquid that is widely used in various industrial and laboratory applications. It serves as a solvent, fuel, and chemical intermediate. Methanol has a simple chemical formula of CH3OH and a boiling point of 64.7°C. It is a versatile compound that is widely used in the production of other chemicals, as well as in the fuel industry.

Triethylamine by Merck Group

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Triethylamine is a clear, colorless liquid used as a laboratory reagent. It is a tertiary amine with the chemical formula (CH3CH2)3N. Triethylamine serves as a base and is commonly employed in organic synthesis reactions.

Ethanol by Merck Group

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Ethanol is a clear, colorless liquid chemical compound commonly used in laboratory settings. It is a key component in various scientific applications, serving as a solvent, disinfectant, and fuel source. Ethanol has a molecular formula of C2H6O and a range of industrial and research uses.

N n dimethylformamide (dmf) by Merck Group

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N,N-dimethylformamide is a clear, colorless liquid organic compound with the chemical formula (CH3)2NC(O)H. It is a common laboratory solvent used in various chemical reactions and processes.

Hydrochloric acid (hcl) by Merck Group

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Hydrochloric acid is a commonly used laboratory reagent. It is a clear, colorless, and highly corrosive liquid with a pungent odor. Hydrochloric acid is an aqueous solution of hydrogen chloride gas.

Tegdma by Merck Group

Sourced in United States, Germany

TEGDMA is a dimethacrylate-based cross-linking agent used in the formulation of dental and medical adhesives, sealants, and composites. It is a clear, viscous liquid that helps improve the mechanical properties and durability of these products.

Ethylene glycol dimethacrylate by Merck Group

Sourced in United States, Germany, United Kingdom, Canada, Italy, Belgium, Spain, China, France, Singapore

Ethylene glycol dimethacrylate is a chemical compound used as a cross-linking agent in various applications. It is a colorless, viscous liquid with a characteristic odor. The primary function of ethylene glycol dimethacrylate is to create a three-dimensional network structure in polymeric materials, enhancing their mechanical and thermal properties.

Camphorquinone by Merck Group

Sourced in United States, Germany, United Kingdom

Camphorquinone is a chemical compound used in various applications, including as a photoinitiator in dental materials and some adhesives. It is a bicyclic ketone with the chemical formula C₁₀H₁₄O₂. Camphorquinone is known for its ability to initiate the polymerization process when exposed to visible light, making it a critical component in certain types of laboratory equipment and materials.

More about "Glycidyl methacrylate"

Glycidyl methacrylate (GMA) is a versatile epoxy-containing monomer that is widely used in a variety of polymer applications.
This reactive compound can be copolymerized with other monomers, such as azobisisobutyronitrile (AIBN), methanol, triethylamine, ethanol, N,N-dimethylformamide, and hydrochloric acid, to create materials with improved mechanical, thermal, and chemical properties.
GMA is commonly employed in the manufacture of coatings, adhesives, sealants, and composite materials.
Its epoxy functionality allows for crosslinking and grafting reactions, which enhance the performance and durability of the final product.
The incorporation of other monomers, like TEGDMA (triethylene glycol dimethacrylate) and ethylene glycol dimethacrylate, can further improve the properties of GMA-based materials.
Researchers studying GMA can utilize PubCompare.ai, an AI-driven platform, to easily locate the best protocols and products from literature, preprints, and patents.
This helps optimize experiments, improve reproducibility, and enhance the accuracy of their research.
By leveraging the power of PubCompare.ai, scientists can unlock the full potential of their GMA-related studies and develop innovative solutions in a wide range of industries.
Whether you're formulating new coatings, designing adhesives, or creating composite materials, understanding the versatility and applications of glycidyl methacrylate is crucial.
Explore the latest advancements and discover how PubCompare.ai can support your GMA research and development efforts.