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5 protocols using 1 ethyl 3 methylimidazolium chloride emimcl

1

Multiwall Carbon Nanotubes for Electrochemical Devices

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Multiwall carbon nanotubes (MWCNT, Baytubes® C150P; amorphous carbon content 0%) with an average outside diameter of 13 nm, inside diameter of 4 nm, and length over 1 μm were obtained from Bayer Material Science (Leverkusen, Germany) and used as supplied. 1-Ethyl-3-methylimidazolium chloride (EMIMCl, >97%), bis(trifluoromethane)sulfonimide lithium salt (LiTFSI, 99.9%), ethanol (technical), and propylene carbonate (PC, >99%) were purchased from Sigma-Aldrich (Taufkirchen, Germany). Deionized water Milli-Q+ (Tallinn, Estonia) was used as supplied.
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2

Electrochemical Device Fabrication

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Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) pellets (Mw: 400,000, Sigma-Aldrich), poly(methacrylic acid methyl ester) (PMMA) powder (Mw: 996,000, Sigma-Aldrich), Zn(CF3O3S)2 powder (98.0%, Sigma-Aldrich), 1-Ethyl-3-methylimidazolium chloride ([EMIM]Cl) (98.0%, Sigma-Aldrich), ZnCl2 (≥98%, Sigma), [EMIM]CF3O3S ( ≥ 98%, Sigma-Aldrich), [EMIM][TFSI] (≥98%, Sigma-Aldrich), Li[TFSI] (99.95%, Sigma-Aldrich), acetone (≥99.8%, Fisher Chemical), acetonitrile (≥99.9%, Fisher Chemical), propylene carbonate (PC) (99.7%, Sigma-Aldrich), fluorine-doped tin oxide (FTO) glass, and polytetrafluoroethylene (PTFE) spacers were purchased and directly used without further treatments.
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3

Cellulose-Based Feedstock Utilization

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α-Cellulose as a feedstock was purchased from Sigma-Aldrich (KOREA). The activated carbon, nitric acid (HNO3, 70%) and sulfuric acid (H2SO4, 95–98%) were purchased from Sigma-Aldrich. 1-Ethyl-3-methylimidazolium chloride ([EMIM]Cl, 98%) and 1,3-dimethylimidazolium dimethyl phosphate ([DMIM]DMP, 98%) were purchased from Sigma-Aldrich. Lactic acid and choline chloride were also provided by Sigma-Aldrich.
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4

Cellulose Modification with Imidazolium Ionic Liquids

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1-Ethyl-3-methylimidazolium acetate (EmimOAc) was obtained from Kanto Chemical Co., Inc. (Tokyo, Japan) and was used without further purification. 1-Ethyl-3-methylimidazolium chloride (EmimCl) was purchased from Sigma-Aldrich Co. LLC. (St. Louis, MO, USA) and was used after recrystallization twice from acetonitrile. Cellulose (Avicel® PH-101, particle size < 50 μm) was obtained from Sigma-Aldrich Co. LLC. (St. Louis, MO, USA). The number-average degree of polymerization of Avicel was calculated to be 105.14 (link) All the ILs, except EmimOAc, were synthesized according to conventional protocols. Tetrabutylammonium hydroxide (TBAOH) methanol solution, vinyl propionate, vinyl laurate, vinyl pivalate and vinyl 4-tert-butylbenzoate were purchased from Tokyo Chemical Industry (TCI, Tokyo, Japan). Other chemicals were obtained from commercial sources and were used as-received unless otherwise stated.
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5

Cellulose Biomass Pretreatment and Characterization

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Carboxymethyl cellulose (CMC) (400–800 cps), cellulose powder (Type 20), α-cellulose, Avicel PH101, cellobiose, glucose, glucose assay kit, and ionic liquids such as 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM-BF4), 1-butyl-3-methylimidazolium acetate (BMIM-Ac), and 1-ethyl-3-methylimidazolium chloride (EMIM-Cl) were purchased from Sigma-Aldrich (St. Louis, MO, USA). Phosphoric acid-swollen cellulose (PASC) was prepared from Avicel PH101, as previously described by Zhang et al. (2006 (link)). All cello-oligosaccharide stocks (G2–G6) were purchased from Megazyme (Wicklow, Ireland). Bovine serum albumin (BSA) was purchased from Merck (Darmstadt, Germany). All other reagents were of analytical grade purity and obtained from similar commercial sources.
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