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3 protocols using mgcl2 6h2o

1

Metal-Mediated Bioactive Compound Synthesis

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2,4-difluorobenzoic acid, L-lysine, metal cation compound, and sodium salts (CuSO4, MgCl2·6H2O, CaCl2, ZnCl2, MnCl2, KI, (CH3COO)2Pb, (CH3COO)2Sr, (CH3COO)2Ba, LiCl, CdCl2, AgNO3, CsBr, NaCl, NaF, KHF2, NaBr, Na2SO4, Na2SO3, Na2CO3, NaHCO3, NaNO3, NaNO2, NaH2PO4, and NaH2PO2) were purchased from Macklin Biochemical Co., Ltd. (Shanghai, China) and of at least analytical grade. Deionized water was the solvent of all of the solutions, and all of the reagents were used directly without further treatment.
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2

Heterogeneous Catalysts for Hydrogenation

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MgCl2·6H2O (98.0 %), AlCl3·6H2O (97.0 %) and cyclohexane (99.5 %) were purchased from Shanghai Macklin Biochemical Co., ltd. NaOH (96.0 %) and Na2CO3 (99.8 %) were provided by Tianjin Guangfu Technology Development Co., ltd. Carboxyl-functionalized CNT (diameter 20–30 nm, length 0.5–2 μm) was manufactured by Nanjing Xianfeng Nanomaterials Technology Co., ltd. RuCl3·3H2O and NEC (98 %) were produced by Zhejiang Metallurgical Research Institute Co., ltd. and Beijing Coupling Technology Co., ltd., respectively. H2 (99.999 %) and N2 (99.999 %) were purchased from Harbin Qinghua Industrial Gas Co., ltd. Commercial Ru/Al2O3 (5 wt%) catalyst was produced at Alfa Aesar Chemical Co., ltd.
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3

Alkali Lignin Purification and Characterization

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Alkali lignin with 4% sulfur was acquired from Sigma-Aldrich (Shanghai, China).
3-Aminophenylboronic acid (≥98%) was purchased from Aladdin (Shanghai, China). Other chemicals, including NaCl2, NaF, Na2S, NaNO3, Na2SO3, Na2SO4, NaH2PO2, KCl, NiCl2.6H2O, MgCl2.6H2O, CuCl2.H2O, CaCl2, ZnCl2, FeCl3.6H2O, and K2CrO4 were purchased from Macklin (Shanghai, China). Deionized (DI) water was used throughout this experiment. The dialysis bags with retained molecular weight of 1000 Da were provided by Viskase (USA). The microporous filter membranes of aqueous system with the diameter of 1.0 and 0.10 μm were obtained by Jinteng (Tianjin, China). All chemicals were used without any further purification.
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