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3 protocols using 4 tert butyl aniline

1

Cotton Fabric Magnetite Nanoparticle Coating

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Cotton was furnished through SITEX (International Textile Society, Tunisia) and drabbed using hydrogen peroxide before magnetite nanoparticle coating. Methyl Orange, FeCl2·4H2O, FeCl3·6H2O, Thionylchloride (SOCl2) and NaOH, benzyl, 5-Chloro-salicylaldehyde, pyridin-2-amine, 5-methylpyridin-2-amine and 4-(tert-butyl) aniline are approved chemicals from Sigma-Aldrich (Steinheim, Germany).
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2

Synthesis of Molybdenum Disulfide Composites

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All organic solvents were
high-performance liquid chromatography (HPLC)-grade and used without
further purification. Bulk molybdenum disulfide powder (from ∼6
μm to a maximum of 40 μm, 98%, product number 69860, batch
number WXBD2352V) was purchased from Sigma-Aldrich and used without
further purification. Iron(II) chloride tetrahydrate, cobalt(II) chloride,
zinc(II) chloride, and copper(II) chloride were purchased from Sigma-Aldrich.
4-nitrobenzenediazonium tetrafluoroborate (97%), sodium tetrafluoroborate
(98%), sodium nitrite (reagent plus, ≥99%), nitrobenzene (≥99%),
1,2-dichlorobenzene (anhydrous, 99%), isopentyl nitrite (96%), acetonitrile
(HPLC gradient grade, ≥99.9%), N,N-dimethylformamide (≥99.8%), diethyl ether (HPLC, ≥99.9%,
inhibitor-free), Whatman poly(tetrafluoroethylene) (PTFE) membrane
filters (PTFE membrane circles, TE 36, 0.45 μm, 47 mm), and
4-tert-butylaniline (99%) were purchased from Sigma-Aldrich.
Water used for experiments was ultrapure type I water (18.2 MΩ
cm) from a Millipore Simplicity water purification system.
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3

Synthesis and Characterization of a Novel Fluorescent Compound

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All metal salts, chemicals, reagents and solvents of analytical grade were purchased from commercial sources and used without further puri cation. 4-tert-Butyl aniline and chloroacetyl chloride were obtained from Sigma Aldrich. Fluorescence active TLC plates (F-2009) were obtained from Merck. Fluorescence spectra were recorded on a Jasco FP-8300 spectro uorometer (Tokyo, Japan) with EHCS-813. Absorption spectra were recorded using a Jasco V-750 UV-Vis recording spectrophotometer (Tokyo, Japan) with EHCS-750 in the range of 200-800 nm. 1 H NMR, 13 C NMR, and 13 C DEPT spectra were obtained on a Bruker AV-(III) -400 MHz spectrometer using a BBFO probe. Mass spectra were recorded on a Micromass Q-TOF micro mass spectrometer with a capillary voltage of 3000 V and a source temperature of 120°C.
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