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3 protocols using methylene chloride

1

Characterization of Colorful Electrochromic Materials

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Basic blue 7, basic blue 26, ethyl violet, lithium bis(trifluoromethanesulfonyl)imide, and lithium bis(oxalato)borate were purchased from TCI. Propylene glycol methyl ether acetate was purchased from Sigma-Aldrich. Methylene chloride, chloroform, and other chemical solvents were purchased from Samchun Pure Chemical. All chemicals were used without any additional purification. Transparent glass substrates were provided by Paul Marienfeld GmbH & Co.KG and acrylic binder was supplied by Alphachem Corporation.
Absorption and transmittance spectra were measured using a Perkin Elmer Lambda 25 UV/Vis spectrophotometer. Chromatic characteristics of the color films were analyzed on a Scinco color spectrophotometer. X-ray diffraction patterns were measured using Bruker New D8 Advance X-Ray Diffractometer. 1H and 13C Nuclear Magnetic Resonance (NMR) spectra were recorded on a Bruker Avance 500 spectrometer running at 500 MHz using chloroform-d as a solvent with TMS as an internal standard. Mass spectra were obtained using an LCQ Fleet mass spectrometer with high resolution.
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2

Phytochemical Profiling of Smilax china L. Root

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Smilax china L. root used in this study originated from Gyeongju city, Gyeongsangbuk-do, Korea and was supplied by Hwalim Natural Drug Co., Ltd. (Busan, Korea). C. acnes KCTC 3314 and KCTC3320 strains were purchased from the Korean Collection for Type Cultures (Jeongeup, Korea) and used for antimicrobial activity tests as human skin acne-causing bacteria. The solvents of Ethyl alcohol (95%), Methylene chloride, Ethyl acetate, n-Hexane, MEthyl alcohol (99%), and Trifluoro acetic acid (TFA) were purchased from Samchun Chemical Co., Ltd. (Seoul, Korea). Acetonitrile and Formic acid were purchased from TEDIA (Fairfield, OH, USA) and Daejung Chemical Co. (Goryeong, Korea), respectively. Standard materials of (+)-Catechin hydrate, Chlorogenic acid crystalline, D-Quinic acid (98%), Caffeic acid, OxyResveratrol, Resveratrol, Polydain, and Quercetin were purchased from Sigma-Aldrich, Inc. (St. Louis, MO, USA).
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3

Synthesis and Characterization of Perylene-based Nanocomposites

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Perylene-3,4,9,10-tetracarboxylic dianhydride (97%, Aldrich), methylene chloride (99.5%, Samchun), triethylamine (99%, Samchun), ethylenediamine (≥99%, Aldrich), multi-walled carbon nanotubes (MWNTs, 97%, length: about ∼1 μm, Applied Carbon Nano Co. Ltd.), toluene (99.5%, Samchun), 1,3-dichlorobenzene (DCB, ≥98.0%, Alfa), Ag flake (SF120, Ames Advanced Materials Corporation), polystyrene-polyisoprene-polystyrene (SIS, styrene 22%, 12 poise @ 25 wt% in toluene, Aldrich), sorbitan trioleate (STO, Showa), sorbitan monooleate (SMO, Showa), sorbitan monolaurate (SML, Showa), and (tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane (Gelest) were purchased and used as-received without further purification procedures.
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