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3 protocols using 6 bromohexanoic acid

1

Synthesis of Palladium Nanoparticles

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The following materials were purchased from the indicated suppliers and used as received: Potassium tetrachloropalladate (K2PdCl4), tetra-n-octylammonium bromide (TOAB), 6-bromohexanoic acid and sodium borohydride (NaBH4) were purchased from ACROS. 1-Octen-3-ol was obtained from Alfa Aesar. 1-Nonen-3-ol, 1-decen-3-ol and 8-bromooctanoic acid were purchased from Sigma-Aldrich. Sodium thiosulfate (Na2S2O3.5H2O), phosphate buffered saline (PBS, pH 7.4), toluene, methanol and ethyl alcohol were obtained from Fisher Scientific. Chloroform-d and deuterium oxide were purchased from Cambridge Isotope Laboratories. Water was purified by using a Barnstead NANO pure Diamond ion exchange resins purification unit. Spectra/Por cellulose ester (CE) dialysis membrane (M.Wt. 8,000–10,000 Daltons) were purchased from Spectrum Laboratories, Inc.
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2

Organic Synthesis Protocols

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Glycine (98%), 6-bromohexanoic acid (98%) and 2,3,3-trimethyl-3H indole (98%) were purchased from ACROS (Beijing, People’s Republic of China). Rhodamine123 was purchased from Sigma-Aldrich Co (St Louis, MO, USA). Thin layer chromatography was used to monitor chemical reactions with GF254 silica gel plates. Products were purified with silica gel flash chromatography. Arium pro ultrapure water (18.2 MΩ cm; Sartorius Stedim Biotech GmbH, Goettingen, Germany) was used throughout the analytical experiments.
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3

Synthesis and Characterization of Palladium Nanoparticles

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The following materials were purchased from the indicated suppliers and used as received: Potassium tetrachloropalladate (II) (K2PdCl4), tetraoctylammonium bromide (TOAB), sodium borohydride (NaBH4) and 6-bromohexanoic acid were purchased from ACROS. Dimethyl acetylene dicarboxylate (DMAD) and graphene oxide (GO) [4 mg/mL in H2O] were purchased from Sigma Aldrich. D2O was purchased from Cambridge Isotope Laboratories. Sodium thiosulfate (Na2S2O3·5H2O), toluene, acetone, acetonitrile, methanol, ethanol, chloroform and tetrahydrofurane (THF) were obtained from Fisher Scientific. Spectra/Por cellulose ester (CE) dialysis membranes (M.Wt. = 8,000–10,000 Daltons) were purchased from Spectrum Laboratories, Inc. Water was purified by Barnstead NANOpure Diamond ion exchange resins purification unit.
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