weight (Mn) and dispersity (Đ) of the synthesized polymers and MBM were
obtained using a Viscotek VE2001 size-exclusion chromatography (SEC)
instrument with THF (Optima) as the eluent (1.0 mL min–1) and polystyrene standards (1.78–205 kg mol–1) as the reference. Glass transition temperatures (Tg’s) of all polymers were determined using a differential
scanning calorimeter (DSC, Discovery Series, TA Instruments). The
thermal degradation behavior of SaBSa was characterized using thermogravimetric
analysis (TGA, Discovery Series, TA Instruments). Further details
of thermal analysis are located in the
using dog-bone-shaped testing bars (following ASTM D638, bar type
5, 5.3 mm gauge width, 0.8 mm thickness) that were prepared by compression
molding into a Teflon PTFE sheet (McMaster Carr) on a PHI hot press.
Tensile testing was performed with a RSA-G2 solids analyzer (TA Instruments)
in tension mode. Tensile testing on MBM also was performed for comparison,
except that the testing specimens were prepared with an aluminum mold.
Detailed protocols are provided in the