Bmim ntf2

Manufactured by IoLiTec

BMIM-NTf2 is an ionic liquid compound that is commonly used in laboratory equipment and research applications. It consists of a 1-butyl-3-methylimidazolium cation and a bis(trifluoromethanesulfonyl)imide anion. The compound has a low melting point and high thermal stability, making it suitable for a variety of laboratory procedures.

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2 protocols using bmim ntf2

Ionic Liquids Synthesis and Characterization

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1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
(BMIM-NTf₂, 99%) and 1-butyl-1-methylpyrrolidinium triflate
(BMPYRR-OTf, 99%) were purchased from IoLiTec and used as received.
1-Butyl-3-methylimidazolium trifluoromethanesulfonate (BMIM-OTf, 97%),
K₂PtCl₄ (99.9%), polyvinylpyrrolidone (PVP,
MW = 55,000), ethylene glycol (99.8%), and Fe(NO₃)₃•9H₂O (98%) were all purchased from Sigma-Aldrich
and used as received. 1-Butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide
(BMPYRR-NTf₂, 98%) was purchased from TCI Chemicals and
used as received. Acidified water at different pH levels was prepared
by diluting a nitric acid solution (Supelco, 68–70%) with deionized
(DI) water. The pH values were verified by a pH meter (Jenway 3510).

Pan B., Karadaghi L.R., Brutchey R.L, & Malmstadt N. (2023). A Multistep, Multicomponent Extraction and Separation Microfluidic Route to Recycle Water-Miscible Ionic Liquid Solvents. Industrial & Engineering Chemistry Research, 63(1), 489-497.

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Synthesis of Functionalized Ionic Liquids

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Imidazole (99 % purity), benzyl bromide (98 %), 2-(bromomethyl)naphthalene (96 %), lithium bis(trifluoromethanesulfonyl)imide (99 %), sodium hydride (60% in mineral oil), 1-methylImidazole (99 %) and graphite flakes (+100 mesh particle size, ≥75 % min) were purchased from Sigma Aldrich.
[Bmim][NTf 2 ] (99.5 %) was purchased from IoLiTec. All the ILs reported herein were synthesized and purified in our laboratory, except for [Bmim][NTf 2 ] (IL1). The synthetic procedures and characterizations for [(Bn)mim][NTf 2 ] (IL2), 1-(naphthylmethyl)-3methylimidazolium bis(trifluoromethanesulfonyl)imide, namely [(Np)mim][NTf 2 ] (IL3), and [(Bn) 2 im][NTf 2 ] (IL4) can be found in the supplementary information section (Fig. S4-S6). The synthetic procedure used to prepare 1-(naphthylmethyl)-3-benzylimidazolium bis(trifluoromethanesulfonyl)imide, namely [(Np)(Bn)im][NTf 2 ] (IL5), is described hereafter in section 2.2.

Aldroubi S., Anglaret E., Bou Malham I., Hesemann P., Brun N, & Mehdi A. (2023). Long-term stable solid concentrated graphene dispersion assisted by a highly aromatic ionic liquid. Journal of colloid and interface science, 636.

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