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5 protocols using methyl orange c14h14n3nao3s

1

Spectrophotometric Determination of Titanium

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Ammonium oxalate (C2H8N2O4; 99.5%), sodium bismuthate (NaBiO3; 90%), ascorbic acid (HC6H7O6), titanium(iii) chloride (TiCl3) solution, sodium lauryl sulfate (NaC12H25SO4), and methyl orange (C14H14N3NaO3S) were purchased from Sigma-Aldrich.
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2

Colorimetric Palladium Detection Protocol

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Orthophosphoric acid (H3PO4, ≥ 85%), ammonia solution (NH4OH, ≥ 25%), and potassium iodide (KI, ≥ 99%) were acquired from Friedmann Schmidt. Potassium chloride (KCl, 99.5%) and ethanol (C2H5OH, 95%) were purchased from R&M. Palladium (II) chloride (PdCl2, 99%) and methyl orange (C14H14N3NaO3S, C.I. 13025) were obtained from Sigma Aldrich. In all experiments, deionized water (DI water, 18.2 MΩ·cm) was utilized.
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3

Synthesis of Metal Nitrate Complexes

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Aluminum nitrate nonahydrate (Al(NO3)3·9H2O), magnesium nitrate hexahydrate (Mg(NO3)2·6H2O), urea (CH4N2O), sodium bicarbonate (NaHCO3), and methyl orange (C14H14N3NaO3S) were purchased from Sigma-Aldrich Co., LLC. (St. Louis, MO, USA). Sodium hydroxide (NaOH) in pellet form was purchased from Daejung Chemicals & Metals Co., Ltd. (Siheung, Republic of Korea). All reagents were used without further purification.
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4

Photodegradation Evaluation of Metal-Doped Catalysts

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The chemicals and reagents included zinc acetate dehydrate ((CH3COO)2Zn·2H2O) (Research lab, India, 98%), ethanol (C2H5OH) (Merck, Germany, 99.5%), copper (II) nitrate trihydrate (Cu(NO3)2·3H2O) (Merck, India, 99%), sodium hydroxide (NaOH) (Merck, Germany, 98%), nitric acid (HNO3) (Merck, Germany, 65%), nickel nitrate hexahydrate (Ni(NO3)2·6H2O) (Merck, Germany, 95%), and acetone (C3H6O) (Merck, India, 99.5%). All chemicals were analytical grade and required no further purification. Methyl orange (C14H14N3NaO3S) (USA, dye content 85%) was utilized as a model dye to assess the photodegradation activity and purchased from Sigma-Aldrich. Ultrapure water was used as a solvent for preparing the solution throughout every experiment.
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5

Methyl Orange Degradation Optimization

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Analytical grade chemicals have been employed. Methyl Orange (C14H14N3NaO3S, dye content 85%, Sigma-Aldrich) played a role as model contaminant, whereas sodium sulfate (Karal) was added to ensure a high conductivity. Ferrous sulfate heptahydrate added as catalyst in EF and PEF was supplied by Fermont. All synthetic solutions were prepared with three-distilled water at room temperature (298  2 K). The pH of the solutions was adjusted with diluted NaOH and H 2 SO 4 solutions, both reagents acquired from Fermont. Carboxylic acids used as standards were from Sigma-Aldrich. The solvents used for high-performance liquid chromatography (HPLC) analysis were of chromatographic grade from Karal.
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