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5 protocols using formamidinium bromide

1

Synthesis of Hybrid Perovskite Materials

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Methylammonium bromide (MABr, 98%), formamidinium bromide (FABr, ≥98%), cesium bromide (CsBr, 99.999% trace metals basis), lead bromide (PbBr2, 99.99%), N-N-dimethylformamide (DMF, suitable for HPLC, ≥99.9%), n-hexane (hexane, suitable for HPLC, ≥97.0%), toluene (suitable for HPLC, 99.9%), chloroform (≥99.5%), oleic acid (OA, 90%), oleylamine (OLA, 70%), and methyl acetate (anhydrous, 99.5%) were purchased from Sigma-Aldrich and used directly without further purification.
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2

Synthesizing Hybrid Perovskite Materials

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Formamidinium bromide (FABr),
ethylammonium bromide (EABr), and lead bromide (PbBr2)
were ordered from Sigma. Dimethyl formamide (DMF) and toluene were
purchased from Alfa-Aesar.
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3

Perovskite Materials Synthesis and Characterization

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Methylammonium bromide (MABr, 99.9%, Dyesol), methylammonium iodide (MAI, 99.9%, Dyesol), formamidinium bromide (FABr, 99.9%, Dyesol), formamidinium iodide (FAI, 99.9%, Dyesol), cesium bromide (CsBr, Sigma-Aldrich, 99%, metals basis), lead(ii) bromide (PbBr2, Sigma-Aldrich, 99%, metals basis), lead(ii) iodide (PbI2, Sigma-Aldrich, 99%, metals basis), octylamine (Aladdin, 99.5%), oleic acid (Aladdin, 99.5%), hexane (Sigma-Aldrich, 95%), toluene (Sigma-Aldrich, anhydrous, 99.8%), chlorobenzene (Sigma-Aldrich, 99.9%).
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4

Synthesis of Perovskite Materials

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Chemicals including lead
bromide (PbBr2, ≥98%), formamidinium bromide (FABr,
≥98%), rubidium bromide (RbBr, 99.6%), potassium bromide (KBr,
≥99%), oleic acid (technical grade, 90%), oleylamine (technical
grade, 70%), dimethylformamide (DMF, 99.8%), chloroform (≥99%),
toluene (99.8%), hexane (≥95%), and acetonitrile (99.8%) were
purchased from Sigma-Aldrich. All of the chemicals were directly used
as received without further purification.
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5

Perovskite Precursor Compounds Synthesis

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The
following materials were used: methylammonium
iodide (Sigma, 98%), formamidinium iodide (Sigma, 98%), formamidinium
bromide (Sigma, 98%), formamidinium chloride (Sigma, 97%), CsI (Fischer,
99.9%), CsBr (Fischer, 99.9%), CsCl (Acros, 99.99%), SnI2 (Sigma, 99.999%), SnBr2 (Sigma), SnCl2 (Sigma,
98%), SnI4 (Sigma, 99.999%), and SnBr4 (Sigma,
99%).
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