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8 protocols using tin chloride dihydrate

1

Methylammonium Iodide Perovskite Synthesis

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Methylammonium iodide (MAI, 99.995%) was purchased from GreatCell Solar. Tin chlo-ride dihydrate (SnCl2·2H2O, 98%), lead iodide (PbI2, 99%), chlorobenzene (CB, 99.80%), 4-tert-Butylpyridine (4tBp, 98%), bis(trifluoromethane)sulfonimide lithium salt (Li-TFSI, 99%), acetonitrile (ACN, 99.80%), methylamine solution (MA, 33 wt% in ab-solute ethanol), and acetone (99.80%) were purchased from Merck. 2,2′,7,7′-Tetrakis-(N,N-di-4-methoxyphenylamino)-9,9′-spirobifluorene (Spiro-MeOTAD, 99.50%) and potassium hydroxide pellets (KOH, 85%) were purchased from Lumtec and ACS reagent, respectively. 2-Propanol (IPA, 99.80%) and ethanol (96.3%) were purchased from a local supplier. Gold (Au, 99.99%) was purchased from Kurt. J. Lesker. All the chemicals were used as received without any treatment.
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2

Perovskite Solar Cell Fabrication

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SnO2 NP colloid dispersion (15
wt % colloidal dispersion in H2O) is purchased from Alfa
Aesar. Methylammonium iodide (MAI, 99.995%) is purchased from GreatCell
Solar. Tin chloride dihydrate (SnCl2·2H2O, 98%), lead iodide (PbI2, 99%), 4-tert-butylpyridine (4tBp, 98%), chlorobenzene (CB, 99.80%), bis(trifluoromethane)sulfonimide
lithium salt (Li-TFSI, 99%), methylamine solution (MA, 33 wt % in
absolute ethanol), acetonitrile (ACN, 99.80%), and acetone (99.80%)
are purchased from Merck. 2,2′,7,7′-Tetrakis-(N,N-di-4-methoxyphenylamino)-9,9′-spirobifluorene
(Spiro-MeOTAD, 99.50%) and (6,6)-phenyl C71 butyric acid methyl ester
(PC71BM) are purchased from Lumtec. Potassium hydroxide
pellets (KOH, 85%) are purchased from ACS reagent. 2-Propanol (IPA,
99.80%) and ethanol (96.3%) are purchased from a local supplier. MoOx, Al, and Ag are purchased from Kurt. J. Lesker.
Patterned PET/ITO substrates (48 Ω sq–1) are
purchased from Mekoprint. All of the chemicals are used as received.
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3

Solvothermal Synthesis of Tin Sulfide

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Iron(III) acetylacetonate
(Fe(acac)3 ≥ 99.9% trace metals basis), poly(vinylpyrrolidone)
(PVP, average molecular weight 40,000 g mol–1), N,N-dimethylformamide (DMF), sulfur powder
(99.99%), and tin chloride dihydrate (SnCl2·2H2O, 99%), were purchased from Sigma-Aldrich. All other chemicals
were of analytical grade and used as received from commercial sources
without further purification.
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4

Synthesis and Characterization of Tin-Based Catalysts

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Tin chloride dihydrate (SnCl2·2H2O; 98% purity) and commercial tin oxide (SnO2; 99% purity) were purchased from Sigma-Aldrich Co., St. Louis, MO, USA. Citric acid monohydrate (C6H8O7·H2O; 99.5% purity) and potassium hydroxide (KOH; 85% purity) were obtained from Friendemann Schmidt, Washington, USA. Concentrated chlorosulfonic acid (HSO3Cl; 99% purity) and hydrochloric acid (HCl; 37% purity) were supplied by R&M Chemicals. Other analytical grade solvents such as methanol (CH3OH; 99.9% purity), ethanol (C2H5OH; 99.9% purity), n-hexane (C6H14; 98% purity), isopropanol (C3H8O; 99.8% purity), toluene (C7H8; 99.5% purity), and acetone (C3H6O; 99.5% purity) were provided by Merck KGaA, Darmstadt, Germany. All the chemicals were used as received without any purification. The reference standards of FAME (methyl oleate, methyl linoleate, methyl palmitate, methyl myristate and methyl stearate) and internal standard (methyl heptadecanoate) with 99.9% purity were purchased from Fluka Analytical, USA. The PFAD feedstock was supplied by Jomalina R&D, Sime Darby Sdn. Bhd., Klang, Selangor, Malaysia and the feedstock properties were analysed according to the American Oil Chemists' Society (AOCS) guidelines, including moisture content (AOCS Ca 2b-38), saponification value (AOCS TI 1a-64) and acid value (AOCS Cd 3d-63).
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5

Synthesis of Indium-Tin Oxide Nanoparticles

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The chemicals used in this study were indium
nitrate hydrate (In(NO3)3·xH2O, 99.99%, Sigma-Aldrich), tin chloride dihydrate (SnCl2·2H2O, ≥98%, Sigma-Aldrich), ethylenediaminetetraacetic
acid (H4EDTA, ≥99%, Sigma-Aldrich), polyethylenimine
(PEI, branched, Mw = ∼25,000, Sigma-Aldrich),
and ammonia solution (25.0–30.0%, Samchun). Deionized water
(DI water) was obtained using an 18.2 MΩ (VIVAGEN EXL3) system.
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6

Synthesis of Capping Agents for Nanoparticles

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Tin chloride dihydrate (SnCl2–2H2O), sodium hydroxide (NaOH), hydrochloric acid (HCl), propylene glycerol (C3H8O2), thiourea (CH4N2S), zinc acetate dihydrate (Zn(ac)2.2H2O), Rhodamine 6G (R6G), l-Cysteine (L-Cys), 3-mercaptopropionic acid (MPA) and glutathione (GSH) were purchased from Sigma–Aldrich, South Africa. All chemicals were of analytical grade and used without further purification.
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7

Synthesis of Quantum Dot Nanocomposites

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Tin chloride dihydrate (SnCl2·2H2O), hexamethylenetetramine (HMTA, C6H12N4), cadmium acetate dihydrate (Cd(CH3COO)2·2H2O), sodium sulfide (Na2S), sulfur (S) and potassium chloride (KCl) were obtained from Sigma-Aldrich Co., South Korea and used as such without purification. TiO2 paste (Ti-nanoxide HT/SP) was supplied by Solaronix.
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8

Synthesis of Tin(II) Chloride Hydrate

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All reagents were of analytical
grade and used without further purification. Tin chloride dihydrate
(SnCl2·2H2O), sodium hydroxide (NaOH),
HMT [H2N (CH2)6NH2], and
absolute ethanol were purchased from Sigma-Aldrich, Johannesburg,
South Africa.
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