Acetonitrile d3

Manufactured by Merck Group

Sourced in United States, Belgium, Germany

Acetonitrile-d3 is a deuterated solvent commonly used in nuclear magnetic resonance (NMR) spectroscopy. It is a clear, colorless liquid with a high purity level. Acetonitrile-d3 is often employed as a reference standard and solvent in the analysis of organic compounds using NMR techniques.

Automatically generated - may contain errors

Lab products found in correlation

13 protocols using acetonitrile d3

Trace Element Analysis Protocol

Check if the same lab product or an alternative is used in the 5 most similar protocols

CoCl₂·6H₂O (analytical grade), Co(NO₃)₂·6H₂O (99%), ethylene glycol (99.9%), p-cymene
(99%), nitric acid (70%), tetraethylammonium chloride (98%), tetraethylammonium
nitrate (99%), and tetraethylammonium hydrogen sulfate (99%) were
purchased from Acros Organics (Geel, Belgium). Co, Sm, and Ga standard
solutions (1000 ± 10 mg L^–1) were purchased
from Chem-Lab (Zedelgem, Belgium). Acetonitrile-d₃ (99.9%), Triton X-100 (for molecular biology), and 1-ethyl-3-methylimidazolium
chloride (>95%) were obtained from Sigma-Aldrich (Diegem, Belgium).
Cyanex 923 was purchased from Solvay (Vlaardingen, Netherlands). Isopropanol
(analytical reagent) and LiCl (analytical reagent grade) were supplied
by Fisher Scientific (Merelbeke, Belgium). SmCl₃·6H₂O (99.9%) was ordered from Strem Chemicals (Newburyport, MA).
A silicone solution in Isopropanol for the treatment of the TXRF quartz
glass carriers was obtained from SERVA Electrophoresis GmbH (Heidelberg,
Germany). Choline chloride (98%) was purchased from J&K Scientific
(Pforzheim, Germany). 1-Butyl-1-methylpyrrolidinium chloride (99%)
was obtained from IoLiTec (Heilbronn, Germany). Tetraethylammonium
bromide (99%) was ordered from J. T. Baker Chemicals (Deventer, Netherlands).

Li Z., Onghena B., Li X., Zhang Z, & Binnemans K. (2019). Enhancing Metal Separations Using Hydrophilic Ionic Liquids and Analogues as Complexing Agents in the More Polar Phase of Liquid–Liquid Extraction Systems. Industrial & Engineering Chemistry Research, 58(34), 15628-15636.

+ Open protocol

+ Expand

Oligonucleotide Annealing Protocol

Check if the same lab product or an alternative is used in the 5 most similar protocols

8-MOP and 5-MOP were purchased from TCI (Tokyo, Japan, >98%) and TMP from Sigma-Aldrich (Steinheim, Germany, ≥98%). The lyophilized oligonucleotide 5′-(TA)₂₀-3′ was purchased from Sigma-Aldrich. The manufacturer purified the sample by HPLC. Annealing of the oligonucleotide strands in solution was performed within 24 h before the measurements by heating the solution in a water bath up to 93 °C and letting it cool down to room temperature within several hours. Solvents used were pure water (Fisher Chemical, Loughborough, UK, HPLC gradient grade), deuterium oxide (Deutero GmbH, Kastellaun, Germany, 99.9% D) and acetonitrile-d3 (Sigma-Aldrich, ≥99.8% D). Solutions of the oligonucleotides were buffered with PBS (Sigma Aldrich, one tablet dissolved in 200 mL yielded 10 mM phosphate buffer, 2.7 mM potassium chloride, 137 mM sodium chloride, pH 7.4 at 25 °C).

Diekmann J., Theves I., Thom K.A, & Gilch P. (2020). Tracing the Photoaddition of Pharmaceutical Psoralens to DNA. Molecules, 25(22), 5242.

+ Open protocol

+ Expand

Deuterated Solvents Preparation

Check if the same lab product or an alternative is used in the 5 most similar protocols

Commercially available deuterated benzene-d6 (ACROS organics), methanol-d3, dimethyl sulfoxide-d6, acetonitrile-d3, deuterium oxide (Sigma-Aldrich), toluene, xylene, and chlorobenzene (Kanto Kagaku) were used without further purification.

Oka K., Shibue T., Sugimura N., Watabe Y., Winther-Jensen B, & Nishide H. (2019). Long-lived water clusters in hydrophobic solvents investigated by standard NMR techniques. Scientific Reports, 9, 223.

+ Open protocol

+ Expand

Ruthenium(II) Complexes Synthesis and Characterization

Check if the same lab product or an alternative is used in the 5 most similar protocols

All materials were used as received without further purification unless otherwise noted. Diethyl ether, acetone, acetonitrile, and methanol were procured from Fisher Scientific, and dichloromethane was obtained from Macron Fine Chemicals. N,N-Dimethylformamide was purchased from Sigma-Aldrich and was dried under nitrogen by passing through a column of activated alumina. Reineke salt, ammonium hexafluorophosphate, lithium chloride, sodium chloride, sodium acetate trihydrate, ascorbic acid, 1,3-diphenylisobenzofuran (DPBF), acetylacetonate, 1,10-phenanthroline, 4,4′-dimethylbipyridyl, acetonitrile-d₃ and acetone-d₆ were purchased from Sigma-Aldrich, and 2,2′-bipyridine was obtained from Alfa Aesar. Sulfuric acid and sodium bicarbonate were received from Fisher Scientific, and potassium ferrioxalate was purchased from Strem Chemicals. Neutral alumina was purchased from Fisher Scientific. The starting material [Ru(p-cymene)Cl₂]₂,21 (link) and the complexes [Ru(p-cymene)(bpy)Cl]Cl, [Ru(p-cymene)(4,4′-Me₂bpy)Cl]Cl, [Ru(p-cymene)(phen)Cl]Cl, and Ru(p-cymene)(acac)Cl were synthesized according to published procedures.21b

Al-Afyouni M.H., Rohrabaugh TN J.r., Al-Afyouni K.F, & Turro C. (2018). New Ru(ii) photocages operative with near-IR light: new platform for drug delivery in the PDT window †Electronic supplementary information (ESI) available. CCDC 1841086–1841088. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc02094a. Chemical Science, 9(32), 6711-6720.

+ Open protocol

+ Expand

NMR Measurements with Deuterated Solvents

Check if the same lab product or an alternative is used in the 5 most similar protocols

For all NMR measurements, we used deuterated solvents from Sigma Aldrich: Chloroform-d (99.8 atom % D), Methanol-d4 (99.8 atom % D) and Acetonitrile-d3 (99.8 atom % D).

Gutowska N., Seliger P., Romański J., Zięba M., Adamus G, & Kowalczuk M. (2019). Mass Spectrometry Reveals Complexing Properties of Modified PNP-Lariat Ether Containing Benzyl Derivative of (S)–Prolinamine. Molecules, 25(1), 136.

+ Open protocol

+ Expand

Synthesis and Characterization of Ethylammonium Nitrate

Check if the same lab product or an alternative is used in the 5 most similar protocols

Ethylamine (70 wt% in water), ethanol (analytical reagent) and dimethyl sulfoxide (analytical reagent) were purchased from Fisher Scientific (Merelbeke, Belgium); nitric acid (65%), tri‐n‐butyl phosphate (>99%), formamide (99%), Co(NO₃)₂·6H₂O (99%) and gallium standard solution (1,000 ± 10 mg·L⁻¹) were supplied by Chem‐lab (Zedelgem, Belgium); n‐decane (99%), ethylene glycol (99.5%) and Ni(NO₃)₂·6H₂O (99%) were obtained from Acros Organics (Geel, Belgium); LiNO₃ (99%), Mn(NO₃)₂·4H₂O (>97%), Zn(NO₃)₂·6H₂O (99%), Triton™ X‐100 (for molecular biology), CDCl₃ (99.8%) and acetonitrile‐d₃ (99.9%) were obtained from Sigma‐Aldrich (Diegem, Belgium); Fe(NO₃)₃·9H₂O (99%) was provided by VWR Chemicals (Leuven, Belgium); Cu(NO₃)₂·6H₂O (99.5%) was purchased from BDH Chemicals (Poole, UK). Milli‐Q water (18.2 MΩ∙cm at 25°C) was used to prepare the aqueous solutions. Ethylammonium nitrate was prepared from ethylamine and nitric acid by a simple acid‐base reaction²⁷ and dried on a Schlenk line to a final water content of <0.5 wt%. Drying of protic ionic liquids with nitrate ions, such as EAN, has to be done very carefully.²⁸

Li Z., Zhang Z., Onghena B., Li X, & Binnemans K. (2021). Ethylammonium nitrate enhances the extraction of transition metal nitrates by tri‐n‐butyl phosphate (TBP). Aiche Journal. American Institute of Chemical Engineers, 67(7), e17213.

+ Open protocol

+ Expand

Characterization of Synthetic Compounds

Check if the same lab product or an alternative is used in the 5 most similar protocols

Compound 1 (98%) was supplied by Aldrich Chemical Company whereas 2 (99%) and 3 (99%) by Sigma-Aldrich. Acetonitrile (ACN, HPLC 99.5%) and ethanol (99.8%) were provided by Sintorgan and Merck, respectively. Water was purified using a reverse osmosis RIOS 5 and Synergy (Millipore) (resistivity 18.2 MΩcm, DOC <0.1 mg L⁻¹). Acetone-d₆ and acetonitrile-d₃ were used to obtain the NMR spectra, both provided by Sigma-Aldrich. All solvents and chemicals were used as received without further purification.

Cooke M.V., Chans G.M., Argüello G.A, & Peláez W.J. (2020). Photolysis, tautomerism and conformational analysis of dehydroacetic acid and a comparison with 2-hydroxyacetophenone and 2-acetyl-1,3-cyclohexanodione. Heliyon, 6(7), e04457.

+ Open protocol

+ Expand

Solvent and Reagent Acquisition for Analytical Chemistry

Check if the same lab product or an alternative is used in the 5 most similar protocols

Dichloromethane, ethyl acetate, n-butanol, n-hexane, acetone, acetonitrile, acetonitrile far UV and methanol (all HPLC grade) were purchased from Fisher Scientific (Leicestershire, UK).
All reagents, such as sulphuric acid and formic acid (eluent additive for HPLC) were purchased from Acros Organics (Geel, Belgium) or Sigma-Aldrich (St. Louis, MO, USA). acetonitrile and formic acid (both for UPLC-MS) were obtained from Biosolve Chimie (Dieuze, France).
Ultrapure water was obtained using a Milli-Q system from Millipore (Bedford, MA, USA).
NMR deuterated solvents (CDCl3, acetonitrile-d3, methanol-d4, DMSO-d6, pyridine-d5) were obtained from Sigma-Aldrich.

Baldé M.A., Tuenter E., Matheeussen A., Traoré M.S., Cos P., Maes L., Camara A., Diallo M.S.T., Baldé E.S., Balde A.M., Pieters L, & Foubert K. (2021). Bioassay-guided isolation of antiplasmodial and antimicrobial constituents from the roots of Terminalia albida. Journal of ethnopharmacology, 267.

+ Open protocol

+ Expand

Antioxidant Compounds Characterization

Check if the same lab product or an alternative is used in the 5 most similar protocols

Acetic acid was purchased from Carl Roth GmbH + Co., KG (Karlsruhe, Germany). Acetonitrile, ethyl acetate, and methanol were purchased from VWR International GmbH (Darmstadt, Germany). Acetonitrile-d₃, 2,2′-azinobis(3-ethylbenzothiazoline-6-suflonate), caffeic acid, chlorogenic acid, and potassium persulfate were purchased from Sigma-Aldrich Chemie GmbH (Steinheim, Germany). Ferulic acid, hydrocaffeic acid, and para-coumaric acid were purchased from Fluka Chemicals Ltd. (Wales, UK). Potassium dihydrogen phosphate and potassium hydrogen phosphate were purchased from Merck KGaA (Darmstadt, Germany).

Bork L.V., Rohn S, & Kanzler C. (2022). Characterization of Colorants Formed by Non-Enzymatic Browning Reactions of Hydroxycinnamic Acid Derivatives. Molecules, 27(21), 7564.

+ Open protocol

+ Expand

Electrochemical Conversion of Biomass Derivatives

Check if the same lab product or an alternative is used in the 5 most similar protocols

Sodium bicarbonate, sodium carbonate, and DMF were obtained from Alfa Aesar. HMF, 5‐MF, DMTHF, DHMTHF, sulfuric acid, benzyl alcohol, acetonitrile (HPLC gradient grade), and acetonitrile‐d3 (≥99.8 at.% D) were purchased from Sigma Aldrich. DHMF was obtained from Cayman Chemical and MFA from Acros Organics. All solutions were prepared using ultrapure (18 MΩ cm) water from a Milli‐Q IQ 7000 system (Merck). GC plates were obtained from HTW Germany. BDD electrodes were purchased from Condias and details on the material characteristics can be found in the work by Hutton et al.^[24] Graphite foil was purchased from Alfa Aesar and Ir mixed metal oxide (MMO) plates as counter electrodes were obtained from Metakem.

Kloth R., Vasilyev D.V., Mayrhofer K.J, & Katsounaros I. (2021). Electroreductive 5‐Hydroxymethylfurfural Dimerization on Carbon Electrodes. Chemsuschem, 14(23), 5245-5253.

+ Open protocol

+ Expand

About PubCompare

Our mission is to provide scientists with the largest repository of trustworthy protocols and intelligent analytical tools, thereby offering them extensive information to design robust protocols aimed at minimizing the risk of failures.

We believe that the most crucial aspect is to grant scientists access to a wide range of reliable sources and new useful tools that surpass human capabilities.

However, we trust in allowing scientists to determine how to construct their own protocols based on this information, as they are the experts in their field.

Ready to get started?

Revolutionizing how scientists
search and build protocols!