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4 protocols using pt acac 2

1

Synthesis of Nanoparticles using Oleylamine

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Oleylamine (OAm, >70%) and hexane (99.5%), were both purchased from Tokyo Chemical Industry Co. Ltd., Shanghai. Pt(acac)2 (99.99%), Nafion (5% w/w solution) were all obtained from Alfa Aesar. Ammonium fluoride (≥96%), Ammonium chloride (≥99.5%), Ammonium bromide (≥99%), chloroform (≥99%) and ethanol (≥99.5%) were all purchased from Sinopharm Chemical Reagent Co. Ltd. All the chemicals were of analytical grade and used as received without further purification.
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2

Synthesis of Pt-Ni Electrocatalysts

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Analytical grade benzyl alcohol, benzoic acid, sodium borohydride and nickel nitrate were obtained from Beijing Chemical Reagents, China. Pt(acac)2 (99%), Ni(acac)2 (99%) and PVP (molecular weight (MW)=8,000, analytic reagent (AR)) were purchased from Alfa Aesar. Nafion was acquired from Sigma-Aldrich. All of the chemicals used in this experiment were of analytical grade and used without further purification.
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3

Synthesis of Organic Compounds

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Analytical grade benzyl alcohol was obtained from Beijing Chemical Reagents, China. Pt(acac)2 (99%), Ni(acac)2 (99%), PVP (molecular weight (MW)=8,000), nitrobenzene, benzaldehyde, benzoic acid, styrene, 2,4,6-trimethylstyrene, trans-stilbene, biphenyl, anisole and Platinum (5% on carbon) were purchased from Alfa Aesar. 2,5-dihydroxyterephthalic acid, 4,4′-dimethyl-trans-stilbene and 1-chloro-2-nitrobenzene were acquired from TCI. Aniline was purchased from J.K Scientific. All of the chemicals used in this experiment were analytical grade and used without further purification.
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4

Synthesis of Pt-Ni Alloy Catalysts

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All reagents were of analytical grade and used as purchased, without further purification. Platinum acetylacetonate (Pt(acac)2) and nickel acetylacetonate (Ni(acac)2) were purchased from Alfa Aesar. Polyvinylpyrrolidone (PVP) and molybdenum disulfide nanosheets (MoS2, 100 nm) were purchased from Macklin. N, N−dimethylformamide (DMF) was purchased from Beijing Jingchun Reagent. Ethanol and acetone were purchased from Sinopharm Chemical Reagent Co., Ltd., Shanghai, China.
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