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3 protocols using tartronic acid

1

Synthesis of Nanoparticles for Catalysis

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Glycerol (99%), 1,3-dihydroxyacetone dimer
(97%), glyceraldehyde (90%), methyl glycolate (98%), methyl lactate
(98%), pyruvic aldehyde (40 wt % in H2O), tartronic acid
(97%), gold(III) chloride hydrate (99.999%), poly(vinyl alcohol) (PVA,
MW 9000–10000, 80% hydrolyzed), sodium borohydride (99%), cetyltrimethylammonium
bromide (CTAB, 99%), tetraethyl orthosilicate (TEOS, 98%), tin chloride
pentahydrate (SnCl4·5H2O, 98%), urea (99.5%),
copper oxide, zinc oxide, zirconium oxide, titanium oxide (P25), and
niobium oxide were purchased from Sigma-Aldrich. Hydrotalcite (HT,
Mg/Al = 2) was kindly provided by Kisuma Chemicals BV. USY zeolite
(CBV600, Si/Al = 2.6) was purchased from Zeolyst. Glyceric acid (20
wt % in H2O) was purchased from TCI Chemicals. The H2O used in this work was always of Milli-Q grade. All chemicals
were used without further purification.
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2

Characterization of Organic Acids and Compounds

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The following chemicals, including their sources, purity, and CAS numbers, were used: citric acid monohydrate, Fisher, ACS grade, 5949-29-1; ᴅʟ-malic acid, Alfa Aesar, 98%, 6915-15-7; ᴅʟ-isocitric acid, trisodium salt hydrate, Acros Organics, 95%, 1637-73-6; ᴅʟ-lactic acid, TCI, >85%, 50-21-5; ᴅʟ-glyceric acid, TCI, 20% in water (ca. 2 mol/L), 473-81-4; ᴅʟ-tartaric acid, TCI, >99%, 133-37-9; glutaric acid, Acros Organics, 99% 110-94-1; tricarballylic acid, Alfa Aesar, 98%, 99-14-9; adipic acid, Sigma, 99%, 124-04-9; acetic acid, Sigma, ACS grade, 64-19-7; pimelic acid, Alfa Aesar; >98%, 111-16-0; succinic acid, TCI, >99%, 110-15-6; tartronic acid, Sigma, >97%, 80-69-3; sodium mesoxalate monohydrate, Chemodex, >98%, 31635-99-1; ᴅʟ-2-hydroxybutyric acid sodium salt, Alfa Aesar, >97%, 5094-24-6; ᴅʟ-3-hydroxybutyric acid sodium salt, Chem Impex Int’l Inc., 100.3%, 150-83-4/306-31-0; ascorbic acid, TCI, >99%, 50-81-7; ammonium nitrate, Fisher, ACS grade, 6484-52-2; sodium nitrate, VWR, ACS grade, 7631-99-4; sodium hydroxide, VWR, ACS grade, 1310-73-2; nitric acid, Sigma, ACS grade, 7697-37-2; and sodium azide, Sigma, 99.8%, 26628-22-8. Lacey carbon, 300 mesh, copper grids (product #01895) from Ted Pella, Inc. were used for electron microscopy.
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3

Synthesis and Characterization of Catalytic Nanomaterials

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Acetic acid (Sigma-Aldrich, ≥99.7%); chloroauric acid (Strem, 99.8%); chloroplatinic acid hexahydrate (Sigma-Aldrich, ACS reagent, 37.5% Pt basis); formic acid (Sigma-Aldrich, ≥98%); glyceric acid (TCI, 40 wt. % in water); glycerol (Sigma-Aldrich, ≥99.5%); glycolic acid (Sigma-Aldrich, 99%); concentrated hydrochloric acid (Fisher Scientific, ∼37%); lactic acid (Sigma-Aldrich, 85 wt. % in H 2 O); concentrated nitric acid (Fisher Scientific, 70%); oxalic acid (Sigma-Aldrich, ≥99.99%); phosphoric acid (Sigma-Aldrich, 85 wt. % in H 2 O); polyvinylalcohol (Sigma-Aldrich, 80% hydrolyzed); pyruvic acid (Sigma-Aldrich, 98%); sodium borohydride (Sigma-Aldrich, 99.99%); sodium hydroxide (Fischer Scientific, 99.3%); concentrated sulfuric acid (Fisher Scientific, >95%); tartronic acid (Sigma-Aldrich, ≥97%); Titania P25 (Degussa, ≥99.5%); and water (Fisher Scientific, HPLC grade).
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