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1 pyrenecarboxylic acid

Manufactured by Merck Group
Sourced in United States, Italy

1-pyrenecarboxylic acid is a chemical compound used in various research and analytical applications. It is a polycyclic aromatic hydrocarbon derivative with a carboxylic acid functional group. The compound exhibits fluorescent properties that can be leveraged in spectroscopic techniques. No further details on intended use or applications are provided.

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4 protocols using 1 pyrenecarboxylic acid

1

Synthesis of Fluorescent Silica Nanoparticles

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Example 1

All the chemicals and reagents, including cetyltrimethylammonium bromide (CTAB, ≥98%, Sigma-Aldrich), sodium hydroxide (AG, Fluka), tetraethyl orthosilicate (TEOS, ≥99%, Sigma-Aldrich), 3-aminopropyl triethyl silane (APTS, 99%, Sigma-Aldrich), 1-pyrene carboxylic acid (97%, Sigma-Aldrich), hydroxy benzotriazole (≥97%, Sigma-Aldrich), 1-ethyl-3-(3-dimethyl aminopropyl)carbodiimide hydrochloride (≥99%, Sigma-Aldrich), triethylamine (≥99%, Sigma-Aldrich), ethyl acetate (High-performance liquid chromatography (HPLC), Honeywell) were purchased and utilized without further purification.

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2

Functional Silica Nanoparticle Synthesis

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All the chemicals and reagents, including cetyltrimethylammonium bromide (CTAB, ≥98%, Sigma-Aldrich, St. Louis, MO, USA), sodium hydroxide (≥98%, Fluka, Hampton, NH, USA), tetraethyl orthosilicate (TEOS, ≥99%, Sigma-Aldrich), 3-aminopropyl)triethoxysilane (APTES, 99%, Sigma-Aldrich), 1-pyrenecarboxylic acid (97%, Sigma-Aldrich), hydroxy benzotriazole (≥97%, Sigma-Aldrich), 1-ethyl-3-(3-dimethyl aminopropyl)carbodiimide hydrochloride (≥99%, Sigma-Aldrich), triethylamine (>99%, Sigma-Aldrich), ethyl acetate (≥99.7%, Honeywell, Charlotte, NC, USA), were purchased and utilized without further purification.
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3

Synthesis of Functionalized Silica Microspheres

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11-Bromo-1-undecanol (98%), methacryloyl chloride (96%), 4-methoxyphenol (98%), N,N,N′,N′-tetramethylethylenediamine (98%), N,N-dimethylethanolamine (98%), N,N-dimethylglycine sodium (98%), 2-dimethylaminoethyl chloride hydrochloride (98%), N,N-dimethylpropargylamine (98%), N,N-dimethylallylamine (98%), RhB (95%), fluorescein isothiocyanate (FITC, 95%), 1-pyrenecarboxylic acid (97%), N,N-dimethylethylenediamine (98%), 11-azido-3,6,9-trioxaundecan-1-amine (NH2-EG4-N3, 98%), 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride (EDCI, 96%), 4-dimethylaminopyridine (DMAP, 98%), ACVA (97%), tetraethyl orthosilicate (>99%), and ammonium hydroxide solution [28 weight % (wt %)] were purchased from Sigma-Aldrich and used as received. Silica microspheres (1.0 μm) were purchased from New Mater Nanotechnology. Solvents such as tetrahydrofuran (THF), ethyl ether, acetonitrile, DMSO, dichloromethane (DCM), anhydrous ethanol, and methanol (analytical grade) were purchased from Beijing Chemical Works. DI water (18.2 megohms) was used in all the experiments.
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4

Synthesis and Characterization of Functionalized Graphene Oxide Nanomaterials

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Commercial RGO (1.6 nm thick [akes) was purchased from Graphene Supermarket. 1-pyrenecarboxylic acid (PCA, 97%), n-methyl-2-pyrrolidone (NMP, 99%), tetraoctylammonium bromide (TOAB, 99%), hydrogen tetrachloroaurate(III) trihydrate (HAuCl 4 •3H 2 O, 99.999%), 3,4-dimethylbenzenethiol (DMBT, 98%), sodium borohydride (NaBH 4 , 99.99%), toluene, methanol, l-ascorbic acid (AA), tris[2-carboxyethyl]phosphine hydrochloride (TCEP) and di-sodium hydrogen phosphate dodecahydrate, were purchased from Sigma (Milano, Italy). Potassium chloride, potassium dihydrogenphosphate and other chemicals were acquired from Merck (Milano, Italy).
Water from Milli-Q Water PuriZcation System (Millipore, UK) was used for the preparation of all aqueous solutions.
The measurements were performed in 100 mM phosphate solutions (0.064 M Na 2 HPO 4 •2H 2 O and 0.036 M NaH 2 PO 4 •H 2 O) containing 100 mM KCl at different pH (PS-phosphate saline-solution).
Pasteurized, cow's milk (1.6% fat content) formulae and food for infants from different producers were purchased from local stores.
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