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4 protocols using tetrachloroauric 3 acid hydrate

1

Synthesis of Metal-Thiolate Complexes

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All reagents were purchased commercially and used without further purification. The ligands: 4-Mercaptophenol (97%), 4-Methoxythiophenol (98%) and 4-Aminothiophenol (≥98%) were purchased from Aladdin. Whereas, the ligand 4-Fluorothiophenol (98%) was purchased from Macklin. 4-Mercaptobenzoic acid (90%) was purchased from Adamas Reagent, Ltd. China. Metal salts and metallic oxides: Silver nitrate (AR, ≥99.8%), Sodium hydroxide (AR, ≥96.0%), Tetrachloroauric (III) acid hydrate (AR, ≥47.8%), Copper (II) chloride dehydrate (AR, ≥99.0%) were purchased from Sinopharm Chemical Reagent Co., Ltd, China; Copper (I) oxide (AR, 97.0%) was purchased from Aladdin. Solvents and liquid reagents: Acetonitrile (AR, ≥99.0%), and Ethanol (AR, ≥99.7%) were purchased from Sinopharm Chemical Reagent Co., Ltd, China. Water was purified using the Milli-Q purification system. Hydrogen chloride (AR, 36.0–38.0%, w%) were also purchased from Sinopharm Chemical Reagent Co., Ltd, China.
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2

Preparation of Inorganic Nutrient Solutions

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Tetrachloroauric(III) acid hydrate [HAuCl4·4H2O, analytical grade (AR)], palladium(II) chloride (PdCl2, AR), potassium dihydrogen phosphate (KH2PO4, AR), disodium hydrogen phosphate dodecahydrate (Na2HPO4, AR), ammonium chloride (NH4Cl, AR), magnesium sulfate (MgSO4, AR), sodium chloride (NaCl, AR), ammonium sulfate [(NH4)2SO4, AR], nitrilotriacetic acid [N(CH2CO2H)3, AR], iron(II) sulfate heptahydrate (FeSO4·7H2O, AR), manganese(II) chloride tetrahydrate (MnCl2·4H2O, AR), cobalt(II) chloride hexahydrate (CoCl2·6H2O, AR), copper(II) sulfate pentahydrate (CuSO4·5H2O, AR), zinc chloride (ZnCl2, AR), nickel(II) chloride hexahydrate (NiCl2·6H2O, AR), boric acid (H3BO3, AR), aluminum potassium sulfate dodecahydrate [AlK(SO4)2·12H2O, AR], and sodium molybdate dihydrate (Na2MoO4·2H2O, AR) were purchased from Sinopharm Chemical Reagent Co. Ltd. Sodium selenite (Na2SeO3, 98%) and sodium tungstate dihydrate purum (NaWO4·2H2O, 99%) were supplied by Sigma-Aldrich. In all of the experiments, ultrapure water with a conductivity of 18.2 megohm·cm was used to dissolve and dilute chemical reagents.
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3

Synthesis and Characterization of Metallic Catalysts

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Polyurethane (PU, 8670AU) was purchased from Bayer. Commercial Pd/C catalyst was obtained from Shanghai River Sen Electric Co., Ltd. Potassium hydroxide (KOH, >85%), tetrachloroauric(iii) acid hydrate (AuCl3 HCl·4H2O, >47.8%), sodium borohydride (NaBH4, 98%), l-ascorbic acid (AA, ≥99.7%), trisodium citrate dehydrate (TCD, C6H5Na3O7·2H2O, ≥99.0%), and isopropanol (C3H8O, ≥99.7%) were all obtained from Sinopharm Chemical Reagent Co., Ltd. Hexadecyltrimethyl ammonium bromide (CTAB, 99%), hexadecyltrimethyl ammonium chloride (CTAC, 97%) and sodium tetrachloropalladate(ii) (Na2PdCl4, 98%) were all purchased from Shanghai Aladdin Bio-Chem Technology Co., Ltd. Poly(ethyleneimine) solution (PEI, average Mw ∼2000 by LS, 50 wt% in H2O) was purchased from Sigma-Aldrich Co., Ltd. Alcohol (CH3CH2OH, 99.5%) and hydrochloric acid (HCl, 12 M) were both obtained Tianjin Fuyu Fine Chemical Co., Ltd. All the chemicals were used as received without further purification. The water used in all experiments was ultrapure water prepared by an ultrapure water system (Ulupure, Zhengzhou, China) with a resistivity of 18.25 MΩ cm at room temperature. The quartz tube furnace (OTF-1200X) was purchased from Hefei Crystal Materials Technology Co., Ltd.
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4

Synthesis of Gold Nanoparticles

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Proanthocyanidins were purchased from the Aladdin Reagent Co., Ltd. (Shanghai, China). Tetrachloroauric (III) acid hydrate was obtained from Sinopharm Chemical Reagent Co., Ltd. (Shanghai, China). All other reagents were of analytical purity grade. Ultra-pure water was used throughout this study, and its resistivity was >18 MΩ·cm.
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