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2 protocols using δ cadinene

1

Comprehensive Chemical Sourcing for Analytical Experiments

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Anhydrous
sodium sulfate (AR grade) was purchased from GHTECH (Shantou, Guangdong,
China); dichloromethane (AR grade) was ordered from PN-CHEM (Zhengzhou,
Henan, China). Tridecanol, 2-hexenal, 2-heptanol, (Z)-3-hexenyl acetate,
decanal, and benzyl nitrile were purchased from Sigma (St. Louis,
Missouri, USA); α-farnesene, cis-3-hexenyl hexanoate, 1-hexanol,
(Z)-3-hexenol, benzaldehyde, phytol acetate, ethyl decanoate, 3-octanol,
and guaiacol were obtained from Macklin (Shanghai, China); β-ocimene,
α-copaene, germacrene D, and neophytadiene were purchased from
J&K Chemicals (Shanghai, China); cis-jasmone, caffeine, and (E)-2-hexenol
were obtained from ChemFaces (Wuhan, China); indole was purchased
from Solarbio (Beijing, China); benzyl alcohol, linalool, geraniol,
nerol, nerolidol, α-terpinene, α-humulene, hexadecanoic
acid methyl ester, phytol, phenylacetaldehyde, α-terpineol,
2-phenylethanol, 1-octen-3-ol, δ-cadinene, caryophyllene oxide,
neral, methyl salicylate, and linalool oxide were purchased from Yuanye
Bio-Technology Co. (Shanghai, China). The alkane standard (C6–C44) was purchased from AccuStandard (New Haven,
CT, USA).
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2

Detailed Analytical Standards Protocol

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N-alkane C6-C16 standard (Lot: 563121) for fast GC e-nose was purchased from RESTEK (Bellefonte, PA, USA). N-ketone C4-C9 standard mix for HS-GC-IMS was purchased from Sinopharm Chemical Reagent Beijing Co., Ltd. (Beijing, China). N-alkane C8-C20 standard for HS-SPME-GC-MS was purchased from Sigma-Aldrich Chemical Co., Ltd. (St. Louis, MO, USA). Reference compounds were purchased for identification. Spathulenol (CAS: 6750-60-3, 93%), δ-elemene (CAS: 20307-84-0, 95%), β-elemene (CAS: 515-13-9, 98%), (E)-β-farnesene (CAS: 18794-84-8, 80%), 1-octen-3-ol (CAS: 3391-86-4, 98%), (E)-3-hexen-1-ol (CAS: 928-97-2, 97%), β-caryophyllene (CAS: 87-44-5, 98%), myrcene (CAS: 123-35-3, 98%), (+)-δ-cadinene (CAS: 483-76-1, 95%) and hexyl alcohol (CAS: 111-27-3, 99%) were bought from Shanghai Yuanye Bio-Technology Co., Ltd. (Shanghai, China). Octanal (CAS: 124-13-0, 97%) was provided by Aladdin Biochemical Technology Co., Ltd. (Shanghai, China).
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