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5 protocols using te powder

1

Synthesis of Lead-Sodium Chalcogenide Thermoelectrics

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A polycrystalline ingot of PbS was synthesized
by mixing a stoichiometric ratio of high purity Pb granules (99.999%,
Alfa Aesar) and S powder (99.999%, Alfa Aesar) in a vacuum-sealed
quartz ampoule, followed by reacting them at 1373 K to produce a high-purity
PbS starting material. Polycrystalline ingots of Pb1–xNaxSe0.35S0.1Te0.55 with x = 0.01, 0.02,
0.03, and 0.035 were prepared by mixing appropriate quantities of
the PbS precursor, Pb, Se granules (99.999%, Alfa Aesar), Te powder
(99.999%, Alfa Aesar), and crushed Na chunks (99%, Aldrich) as the
dopant, with a total mass of 10 g for each sample, loaded into carbon-coated
quartz ampoules. The ampoules were sealed under vacuum, then heated
to 1373 K, and held at the same temperature for 10 h. The ampoules
were then quenched in cold water and annealed at 823 K for 72 h.
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2

Synthesis of Chalcogenide Nanomaterials

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All the reagents were of analytical grade and no further purification was performed. The following reagents used were purchased from Sigma-Aldrich, Johannesburg, South Africa: copper (II) chloride (anhydrous, powder, ≥99.995% trace metals basis), zinc chloride (anhydrous, powder, ≥99.995% trace metals basis), tin (II) chloride (anhydrous, powder, ≥99.99% trace metals basis), isopropanol (American Chemical Society, ACS, reagent grade, ≥99.5%), diethylene glycol (analytical grade), sodium borohydride (granular, 99.99% trace metals basis), Te powder (powder, 75 maximum particle size (micron), purity 99.5%), and S powder (powder, 99.98% trace metals basis).
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3

Synthesis and Characterization of Cu(I) Nanoparticles

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Cu (I) Cl, diphenylphosphine (DPP), chloroform, ethanol, dimethylsulfoxide were purchased from Kanto chemicals, Japan. Octadecene and tri-n-butyl phosphine (TBP) were purchased from Tokyo chemical industry, Japan. Te powder, doxorubicin hydrochloride, DCFH-DA and live/dead cell double staining kit were purchased from Aldrich. 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-N-[amino(polyethylene glycol)-2000] (ammonium salt) (DSPE-PEG-Amine) was from Avanti Polar Lipids, Alabama. Alamar blue, Alexafluor Annexin-V 561 and ROS tracer were from Invitrogen. Anti Ki-67 antibody and its secondary antibody were purchased from abcam. All chemicals and reagents were of analytical grade.
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Synthesis of Chalcogenide Semiconductors

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All materials
including SmCl3, InCl3, SbCl3, NaBH4, and Te powder purchased from Sigma Aldrich, having purity
above 99%, were used without further purification.
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5

Synthesis of AuTe2Se4/3 Single Crystals

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Single crystals of AuTe2Se4/3 were grown using the self-flux method. Total 2–4 g starting materials with high purity Au powder (99.99%, Sigma Aldrich), Te powder (99.999%, Sigma Aldrich), and Se powder (99.99%, Sigma Aldrich) were stoichiometrically weighted and sealed in an evacuated silica tube in high vacuum (10−5 mbar) and subsequently mounted into a muffle furnace. The furnace was heated up to 800 °C in 40 h and dwelled 10 h. Afterward, the furnace was slowly cooled down to 450 °C in 4 days and then shut down. Separated crystals from ingot are generally thin with maximum planar size 4 × 1 mm2. The single crystals of AuTe2Se4/3 were ribbon shape with shining mirror-like surfaces.
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