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4 protocols using 2 aminoterephthalic acid nh2 bdc

1

Synthesis of Iron-Based MOF Composite

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All reagents were used directly without further
purification. Iron chloride hexahydrate (FeCl3·6H2O), 2-aminoterephthalic acid (NH2-BDC, 99%), trimethylalumium
(TMA, 99%), acetic acid (AcOH, 97%), rhodamine B (RhB), potassium
dichromate (K2Cr2O7, 99%), 1,5-Diphenylcarbazide
(DPC, 99%) were purchased from Sigma-Aldrich. N,N-dimethylformamide (DMF, 98%) was purchased from Daejung
Chemicals. Nylon microfiber meshes (Figure S1a) with a fiber diameter ranging from 40 to 60 μm were purchased
from APEC (South Korea).
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2

Synthesis and Characterization of Graphene Oxide Composite Materials

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Ethanol (Et-OH), methanol (Me-OH), N, N-dimethylformamide (DMF), hydrochloric acid (HCl), sulfuric acid (H2SO4 98 wt.%), potassium dihydrogen phosphate (KH2PO4), dipotassium hydrogen phosphate (K2HPO4), potassium sulphate (K2SO4), sodium sulphate (Na2SO4), potassium chloride (KCl), calcium nitrate anhydrous (Ca(NO3)2), and hydrogen peroxide (H2O2, 30 wt.%) were received from Sinopharm Chemical Reagent Co., Ltd. (Shanghai, China). Graphene oxide (GO) and titanium isopropoxide (C12H28O4Ti, TPOP 95 wt.%) were purchased from Macklin (Shanghai, China). 2-Aminoterephthalic acid (NH2-BDC, 99 wt.%) was obtained from Sigma-Aldrich Corporation (Shanghai, China), and fenitrothion (assay > 95.8%) was supplied by TM-standard (Jiangsu, China). A working solution of 0.1 M phosphate-buffered solution (PBS) containing 80 mM KH2PO4, 120 mM K2HPO4, and 100 mM K2SO4 was used. The ultrapure water (18.20 MΩ cm) was acquired from Milli-Q plus (Millipore, Billerica, MA, USA).
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3

Fabrication of Ni-based MOF

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The 99% pure reagents and chemicals without further treatment were utilized for synthesis. Prerequisite chemicals for the fabrication purpose include Ni (NO3)2.6H2O, 2-Aminoterephthalic acid (NH2BDC), potassium permanganate (KMnO4), sodium nitrate (NaNO3) which were procured from Sigma Aldrich while Dimethylformamide (DMF), hydrazine hydrate, hydrogen peroxide, and sulphuric acid were picked up from Merck.
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4

Synthesis of NH2-BDC Metal-Organic Framework

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2-Aminoterephthalic acid (NH2-BDC) was purchased from Sigma-Aldrich Co. LLC (Shanghai, China). Ferric trichloride hexahydrate and dimethyl sulfoxide were purchased from Sinopharm Chemical Reagent Co., Ltd. (Shanghai, China). Carboxymethyl cellulose sodium (CMC), tetracycline, EPI (AR), phenolphthalein (AR), and β-CD (1,135 g mol−1, purity >98%) were obtained from Aladdin Industrial Co., Ltd. (Shanghai, China). All other chemicals were of analytical grade, obtained from commercial suppliers, and used without further purification unless otherwise noted.
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