Concerning the PEDOT:PSS single layer on ITO/glass study, the electrochemical analyses were carried out in a three-electrode cell configuration using a BioLogic SP50 potentiostat/galvanostat apparatus (BioLogic SP50, Seyssinet Pariset, France). The counter electrode and reference electrode consisted of a platinum foil and saturated calomel electrode, SCE (ESCE = 0.234 V/NHE), respectively. The operating voltage was controlled between −1.3 V and +1.3 V for chronoamperometry analysis, in a commercial lithium-based ionic liquid, namely EmimTFSI:LiTFSI (9:1 Molar Ratio, Solvionic, 99.9%). All the electrochemical measurements were performed at room temperature. The optical transmittance of PEDOT:PSS thin films was measured in situ using a Varian Cary 5000 UV-vis-NIR spectrophotometer (Agilent, les Ulis, France) between 250 and 800 nm.
Concerning the PEDOT:PSS displays, electrochemical analysis was performed in a two-electrode configuration, using a BioLogic SP50 potentiostat/galvanostat apparatus (BioLogic SP50, Seyssinet Pariset, France). Colorimetry analysis was carried out using a Konica Minolta CM-700D spectrophotometer (Konica Minolta Sensing Europe B.V., Roissy, France), allowing the direct determination of colorimetric parameters of the CIE (L*a*b*) color space.
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