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2 protocols using isobornyl acrylate iba

1

Synthesis and Purification of Polymeric Reagents

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Azobisisobutyronitrile
(AIBN, Sigma-Aldrich) was recrystallized from methanol prior to use.
Isobornyl acrylate (IBA; technical, Sigma-Aldrich) and lauryl acrylate
(LA; >98%, TCI) were passed over a basic alumina column prior to
use
to remove the stabilizer. Methyl acrylate (MA; 99%, Sigma-Aldrich)
was distilled prior to use. Pyridine, dichloromethane (DCM), and triethylamine
were distilled over calcium hydride (CaH2) prior to use.
Cyanomethyl dodecyl trithiocarbonate (CDT) was synthesized according
to a procedure mentioned in the literature.44 (link) 2-(Dodecylthiocarbonothioylthio)-2-methylpropionic acid (DDMAT;
98%, Sigma-Aldrich), trioxane (≥99%, Sigma-Aldrich), biphenyl
(>99%, Sigma-Aldrich), acetophenone (AP; 99%, Sigma-Aldrich), sodium
sulfate (≥99%, Sigma-Aldrich), acetic anhydride (≥99%,
Sigma-Aldrich), trans-2-[3-(4-tert-butylphenyl)-2-methyl-2-propenylidene]-malononitrile (DCTB; Sigma-Aldrich,
>98%), potassium trifluoroacetate (KTFA; Sigma-Aldrich, 98%), acryloyl
chloride (96%, Alfa Aesar), furfuryl alcohol (≥98%, Fischer
Scientific), hydrogen chloride (HCl; 37% solution in H2O, Acros Organics), sodium bicarbonate (>99%, Acros organics),
sodium
chloride (≥99.8%, Roth), tert-butyl methylether
(TBME; 99.9%), acetic acid (AcOH; 99.7%), and CDCl3 (99.8%,
Cambridge Isotope Laboratories) were used as received. All other solvents
were obtained from Biosolve and were used as received.
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2

Functionalized Borosilicate Glass Surfaces

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Borosilicate glass surfaces, in either slide form (Fisher Scientific) or large plate form (McMaster-Carr), were used as the substrates for surface functionalization. Silane coupling agents with different organofunctional groups (Gelest) were all used as received for fabrication of model functionalized surfaces (Table 1). Ethanol (EtOH, Fisher Scientific) was used as received for hydrolysis and condensation of silane coupling agents onto the substrates. Ebecryl 230 (Allnex), isobornyl acrylate (IBA, Sigma-Aldrich), diphenyl (2,4,6-trimethylbenzoyl) phophine oxide (TPO, Sigma-Aldrich), and 2,5-bis(5-tert-butyl-benzoxazol-2-yl) thiophene (BBOT, Sigma-Aldrich) were used as received for the urethane acrylate resin system. Molded polytetrafluoroethylene (PTFE) bars were acquired from McMaster-Carr. All other chemicals in this work were used as received from Sigma-Aldrich.
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