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2 protocols using manganese 2 chloride tetrahydrate

1

Preparation of Inorganic Nutrient Solutions

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Tetrachloroauric(III) acid hydrate [HAuCl4·4H2O, analytical grade (AR)], palladium(II) chloride (PdCl2, AR), potassium dihydrogen phosphate (KH2PO4, AR), disodium hydrogen phosphate dodecahydrate (Na2HPO4, AR), ammonium chloride (NH4Cl, AR), magnesium sulfate (MgSO4, AR), sodium chloride (NaCl, AR), ammonium sulfate [(NH4)2SO4, AR], nitrilotriacetic acid [N(CH2CO2H)3, AR], iron(II) sulfate heptahydrate (FeSO4·7H2O, AR), manganese(II) chloride tetrahydrate (MnCl2·4H2O, AR), cobalt(II) chloride hexahydrate (CoCl2·6H2O, AR), copper(II) sulfate pentahydrate (CuSO4·5H2O, AR), zinc chloride (ZnCl2, AR), nickel(II) chloride hexahydrate (NiCl2·6H2O, AR), boric acid (H3BO3, AR), aluminum potassium sulfate dodecahydrate [AlK(SO4)2·12H2O, AR], and sodium molybdate dihydrate (Na2MoO4·2H2O, AR) were purchased from Sinopharm Chemical Reagent Co. Ltd. Sodium selenite (Na2SeO3, 98%) and sodium tungstate dihydrate purum (NaWO4·2H2O, 99%) were supplied by Sigma-Aldrich. In all of the experiments, ultrapure water with a conductivity of 18.2 megohm·cm was used to dissolve and dilute chemical reagents.
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2

Graphene Oxide-Supported Catalysts Synthesis

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Graphene oxide (GO, thickness, 0.8–1.2 nm) was purchased from Nanjing XFNANO Materials Tech. Co., Ltd and employed as the support. 1,10-Phenanthroline(C12H8N2, 97.0%), Zeolite (Permutit) and γ-Al2O3 were all purchased from Aladdin. Carbon black VX 72 was bought from Cabot Corporation. Acetone, Cobalt(II) chloride hexahydrate (CoCl2·6H2O, 99.0%), Copper(II) chloride dihydrate (CuCl2·2H2O, 99.0%), Manganese(II) chloride tetrahydrate (MnCl2·4H2O, 99.0%), and Palladium(II) chloride (PdCl2, 99.99%) were received from Sinopharm Chemical Reagent Co., Ltd. Rhodium(III) chloride trihydrate (RhCl3·3H2O, 98%), Chloroauric acid (HAuCl4), and Chloroplatinic acid hexahydrate (H2PtCl6·6H2O, 99.99%) were purchased from Shanghai Macklin Biochemical Co., Ltd. Nickel chloride hexahydrate (NiCl2·6H2O, 99.999%), Stannic chloride hydrated (SnCl4·5H2O, 99.995%), and Iridium chloride (IrCl3, 99.8%) were received from Aladdin. All the reagents were used without further purification. Ultrapure Milli-Q water (18.2 MΩ cm−1) was used to prepare all the aqueous solutions and wash samples. Ethanol was received from Shanghai Lingfeng chemical regent Co., Ltd. Pt/C (20 wt%) was purchased from MACKLIN Biochemical Technology Co., Ltd.
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