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2 protocols using trans cinnamic acid

1

Phytochemical standards purification and quantification

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Acetonitrile, methanol, ethanol, silymarin, glucose, and fructose were purchased from Sigma Aldrich (St. Louis, MO, USA), and 4–hydroxyquinoline, salicylic acid, vanillic acid, rutin, trans–4–hydroxycinnamic acid, ellagic acid, sinapinic acid, luteolin, trans–ferulic acid, hesperidin, naringin, 4–hydroxybenzoic acid, and 3,4–dimethoxycinnamic acid (purity > 98%) were purchased from Aladdin (Shanghai, China). Dihydroxybenzoic acid, methyl syringate, fisetin, abscisic acid, quercetin, trans–cinnamic acid, naringenin, apigenin, kaempferol, hesperetin, kaempferide, daidzein, and chrysin (purity > 98%) were obtained from J&K Scientific (Beijing, China). Formic acid was purchased from Merck (Darmstadt, Germany).
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2

Photochemical Reaction Precursor Synthesis

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1,4-Naphthoquinone (99% purity), biacetyl (98% purity), acetophenone (98% purity), coumarin (98% purity), transcinnamic acid (99% purity), 7-hydroxycoumarin (98% purity), naphthalene (99% purity), 2-acetonaphthone (99% purity), 3methoxyacetophenone (99% purity), benzophenone (99% purity), 1,4-benzoquinone (99% purity), riboflavin (98% purity), chlorohydroquinone (85% purity), gallic acid (99% purity) and furfuryl alcohol (98% purity) were obtained from J&K Scientific Ltd. (Beijing, China); dibenzoyl (99% purity), 4-methylbenzaldehyde (98% purity) were purchased from Tokyo Chemical Industry (Tokyo, Japan); duroquinone (97% purity) was obtained from Sigma-Aldrich (St. Louis, MO, U.S.A.). Organic solvents used in this study with chromatographical purity were obtained from TEDIA (Fairfield, OH, USA). Suwannee River fulvic acid (SRFA) was purchased from the International Humic Substances Society. Ultrapure water (PW, 18.2 MΩ) was obtained from a purification system produced by Chengdu Ultrapure Technology Co., Ltd. (Chengdu, China).
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