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2 protocols using 1 4 benzoquinone

1

Radicals Formation Kinetics Study

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As (III)
and As (V) stock
solutions (1.0 g/L), peroxymonosulfate (KHSO5·0.5
KHSO4·0.5 K2SO4), and 5,5-dimethyl-1-pyrroline N-oxide (DMPO) were purchased from J&K Chemical Company.
1,4-Benzoquinone (C6H4O2, BQ), tert-butyl alcohol (C4H10O, TBA),
ethanol (C2H6O, EtOH), humic acid (HA), copper
nitrate (Cu(NO3)2·3H2O), aluminum
nitrate (Al2(NO3)3·9H2O), and citric acid (C6H8O7·H2O) were purchased from Macklin Biochemical Co., Ltd (Shanghai,
China). Details of all reagents mentioned above are listed in Table S6. Stock solutions were always prepared
in ultrapure water produced by a Milli-Q system.
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2

Photochemical Reaction Precursor Synthesis

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1,4-Naphthoquinone (99% purity), biacetyl (98% purity), acetophenone (98% purity), coumarin (98% purity), transcinnamic acid (99% purity), 7-hydroxycoumarin (98% purity), naphthalene (99% purity), 2-acetonaphthone (99% purity), 3methoxyacetophenone (99% purity), benzophenone (99% purity), 1,4-benzoquinone (99% purity), riboflavin (98% purity), chlorohydroquinone (85% purity), gallic acid (99% purity) and furfuryl alcohol (98% purity) were obtained from J&K Scientific Ltd. (Beijing, China); dibenzoyl (99% purity), 4-methylbenzaldehyde (98% purity) were purchased from Tokyo Chemical Industry (Tokyo, Japan); duroquinone (97% purity) was obtained from Sigma-Aldrich (St. Louis, MO, U.S.A.). Organic solvents used in this study with chromatographical purity were obtained from TEDIA (Fairfield, OH, USA). Suwannee River fulvic acid (SRFA) was purchased from the International Humic Substances Society. Ultrapure water (PW, 18.2 MΩ) was obtained from a purification system produced by Chengdu Ultrapure Technology Co., Ltd. (Chengdu, China).
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