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2 protocols using terephthalic acid h2bdc

1

Synthesis and Bioactivity of Functionalized Terephthalic Acid Derivatives

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Zinc nitrate hexahydrate (Zn(NO3)2·6H2O, 99.99%) and N,N-dimethylformamide (DMF, 99.5%) were obtained from Shanghai Aladdin Bio-Chem Technology Co., Ltd. Terephthalic acid (H2BDC) was provided by Tianjin Guangfu Fine Chemical Research Institute. 2-Hydroxymethyl terephthalic acid (98%), 2-bromoterephthalic acid (98%), 2-hydroxyterephthalic acid (98%) and 2-vinyl terephthalic acid (98%) were purchased from Chemsoon Co., Ltd. Triethylamine (TEA, AR) was got from Tianjin Fuchen Chemical Reagent Factory. Methanol (CH3OH, AR) were acquired from Beijing Chemical Factory. Oridonin (ORI, 98%) was supplied by Shanghai yuanye Bio-Technology Co., Ltd. High-glucose Dulbecco's Modified Eagle Medium (DMEM) was offered by Corning. Fetal bovine serum was available from Mediatech (International) Ltd. Dimethyl sulfoxide (DMSO) was taken from Tianjin Guangfu Fine Chemical Research Institute. PBS and penicillin–streptomycin mixture were provided by Solarbio. Fetal bovine serum was supplied by Mediatech (International) Ltd. 3-(4,5-Dimethylthiazol-2-yl)-2,5-dipheny-ltetrazolium bromide (MTT) was furnished from Beijing Biodee Biotechnology Co., Ltd.
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2

Synthesis and Characterization of Zinc-Based MOF

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Zinc nitrate hexahydrate (Zn(NO3)2·6H2O) was purchased from Shanghai Aladdin Biochemical Technology Co., Ltd. (Shanghai, China). Terephthalic acid (H2BDC) and dimethyl sulfoxide (DMSO) were obtained from Tianjin Guangfu Fine Chemical Research Institute (Tianjin, China). Triethylamine (TEA) was acquired from Tianjin Fuchen Chemical Reagent Factory (Tianjin, China). Trichloromethane (CHCl3) and N,N-Dimethylformamide (DMF) were got from Beijing Chemical Factory (Beijing, China). ORI was purchased from Nantong Feiyu Biotechnology Co., Ltd. (Nantong, China). Methanol (Chromatographic reagent grade) was obtained from Thermo Fisher Scientific (Shanghai, China). PBS and penicillin-streptomycin mixture were purchased from Solarbio (Beijing, China). High-glucose Dulbecco’s Modified Eagle Medium (DMEM) was obtained from Corning (Manassas, VA, USA). Fetal bovine serum was available from Zhejiang Tianhang Biotechnology Co., Ltd. (Zhejiang, China). 3-(4,5-dimethylthiazol-2-yl)-2,5-dipheny-ltetrazolium bromide (MTT) was obtained from Beijing Biodee Biotechnology Co., Ltd. (Beijing, China). 4′,6-diamidino-2-phenylindole (DAPI) and Annexin V-FITC Apoptosis Detection Kit were purchased from Shanghai Beyotime Biotechnology Co., Ltd. (Shanghai, China). All chemicals were of analytical grade or higher.
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