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Benzophenone 3 3 4 4 tetracarboxylic dianhydride

Manufactured by Merck Group
Sourced in United States

Benzophenone-3,3′,4,4′-tetracarboxylic dianhydride is a chemical compound used as a raw material in the production of various materials. It has the molecular formula C17H8O7.

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2 protocols using benzophenone 3 3 4 4 tetracarboxylic dianhydride

1

Synthesis of Polyimide Monomers

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The monomers 3,4′-Oxydianiline (3,4′-ODA), 4,4′-(4,4′-Isopropylidenediphenoxy)bis(phthalic anhydride (DA), 4,4′-Oxydiphthalic anhydride (ODPA), 4,4′-(Hexafluoroisopropylidene)diphthalic anhydride (6FDA), 3,3′,4,4′-Biphenyltetracarboxylic dianhydride (BPDA), Benzophenone-3,3′,4,4′-tetracarboxylic dianhydride (BZP), were purchased from Sigma-Aldrich and were used without further purification. The 1,4-Bis(3,4-dicarboxyphenoxy)benzene dianhydride (RDA)) provided by Prof. I. G. Abramov (Yaroslavl State Technical University, Yaroslavl, Russia). Benzoic acid (BA) was crystallized from a water–acetone mixture and dried in vacuo (Tm = 122 °C).
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2

Functionalized EVOH Copolymer Synthesis

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Poly(vinyl alcohol-co-ethylene) (ethylene content = 27%) (EVOH), benzophenone-3,3’,4,4’-tetracarboxylic dianhydride (BD), L-cysteine hydrochloride anhydrous (CYS), hexane, tetrahydrofuran (THF), isopropanol (IPA), and polyphosphoric acid (PPA) were purchased from Sigma-Aldrich (St. Louis, MO, USA). Cysteamine hydrochloride (CA), 1,3-dichloropropene (isomer mixture) (1,3-D), and N, N’-dimethyl-4-nitrosoaniline (p-NDA) were purchased from Spectrum Chemicals & Laboratory Products (Gardena, CA, USA). 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride (EDC) was bought from the Advanced ChemTech (Louisville, KY, USA). Ellman’s reagent (5,5’-dithiobis-(2-nitrobenzoic acid)) was bought from Thermo Scientific (Waltham, MA, USA). Reduced L-glutathione (GSH) and ethane-1,2-dithiol (diSH) were purchased from TCI (Portland, OR, USA). All chemicals were directly used as received.
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