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2 protocols using silver sulfate

1

Carboxymethylation of Alcohols using DMC

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The chemicals and materials used in the DMC mediated carboxymethylation of alcohols were obtained from the commercial suppliers and used without further purification. Dimethyl carbonate (LobaChemie, 99.0%), n-butanol (Merck, 99.0%), tert-butanol (Merck, 99.0%), Iso-butanol (Merck, 99.0%), ethanol (Changshu Hongsheng Fine Chemicals, 99.9%), n-propanol (Merck, 99.0%), cyclohexanol (SDFCL, 95%), H2SO4 (Merck, 95–98%), dichloromethane (DCM) (Merck, 99.5%), methanol (Merck, 99.0%), 1-hexanol (Avra chemicals, 98.0%), 1-octanol (Avra chemicals), benzyl alcohol (Merck, 99.0%), divinylbenzene (DVB) (TCI chemicals), azobisisobutyronitrile (AIBN) (Paras polymers and chemicals, India) and silver sulfate (Lobachemie, 99.0%).
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2

Analytical-Grade Chemical Preparation

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All of the
chemicals used in the present work were of analytical grade and used
as received without any further purification. Potassium dichromate
(99% pure) (K2Cr2O7), sodium hydroxide
(NaOH), Methylene Blue (MB), hydrogen peroxide (30% H2O2), sodium sulfate (Na2SO4), potassium
sulfate (K2SO4), potassium nitrate (KNO3), sodium chloride (NaCl), potassium chloride (KCl), potassium
bromide (KBr), silver sulfate (Ag2SO4), mercuric
sulfate (HgSO4), ferrous ammonium sulfate (FAS), 1,10-phenanthroline,
and 1,5-diphenyl carbazide (DPC) were obtained from Loba Chemie. Hydrochloric
acid (HCl), sulfuric acid (H2SO4), and acetone
were obtained from Qualigens. All of the solutions were prepared in
deionized water obtained from Milli-Q ultrapure water.
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