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2 protocols using ircl3

1

Synthesis and Characterization of Ni-based Catalysts

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The chemicals used in this work, Ni(NO3)2·6H2O (AR, 98%), citric acid (AR, 99.5%), dl-lactic acid (AR, 99%), pyruvic acid (AR, 98%), dl-alanine (AR, 99%), dl-lactamide (98%), NH3·H2O (AR, 28%), RuCl3·nH2O (Ru ≥ 37.5 wt%), IrCl3 (Ir ≥ 60.0 wt%), RhCl3·3H2O (Rh ≥ 39 wt%), H2PtCl2·6H2O (Pt ≥ 37.5 wt%), PdCl2 (Pd ≥ 60.0 wt%), ethylene glycol (AR, 98%), and ethanol (AR, 99.5%) were purchased from Shanghai Macklin Biochemical Co., Ltd. H2SO4 (AR, 98%), formic acid (AR, 88%), acetic acid (AR, 99.8%), and propanoic acid (AR, 99.5%) were purchased from Sinopharm Chemical Reagent CO., Ltd. All the chemicals were used as received without further purification.
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2

Synthesis of Transition Metal Catalysts

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Melamine, FeCl3·6H2O, CrCl3·6H2O, MnCl2·4H2O, NiCl2·6H2O, CoCl2·6H2O, CuCl2·2H2O, H2PtCl6·6H2O, PdCl2, RuCl3, IrCl3, RHCl3·3H2O, Tris-HCl, KOH, dopamine hydrochloride, HCl, KHCO3, and boron nitride were purchased from Shanghai Macklin Biochemical Co., Ltd. 20% Pt/C was obtained from Johnson Matthey (JM) Corp. Nafion-117 membrane and Nafion solution (5 wt.%) were obtained from DuPont. All chemicals were used without further purification. All aqueous solutions were prepared using deionized (DI) water with a resistivity of 18.2 MΩ.
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