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7 protocols using antimony 3 chloride

1

Synthesis of Metal Chloride Compounds

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All chemical reagents used in this study were of analytical grade and were used without further purification. Ruthenium (III) chloride hydrate (RuCl3xH2O–99.5%), antimony (III) chloride (SbCl3–99.0%), hexachloroplatinic acid (H2PtCl6·6H2O–37.5%), oxalic acid (C2H2O4–99.5%), and isopropanol (C3H8O–99.8%) were purchased from Sigma-Aldrich®. (Burlington, MA, USA). Hydrochloric acid (HCl–38.0%) was acquired from Neon® (Suzana, São Paulo, Brazil), sulfuric acid (H2SO4–97%) from Scharlab® (Sentmenat, Spain), and sodium chloride (NaCl–99.5%) from Panreac® (ITW, Chicago, IL, USA). All solutions were prepared using ultrapure water (18.2 MΩcm, 25 °C) from a Gehaka Master All 2000 System (São Paulo, Brazil).
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2

Synthesis of Antimony Nanocrystals

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Oleic acid (OAc, Sigma-Aldrich), oleylamine (OAm, Acros, 80–90%), octadecene (Sigma-Aldrich), octadecene (ODE, Sigma-Aldrich), antimony (III) chloride (ABCR), antimony (III) acetate (Sigma-Aldrich), bis[trimethylsilyl]sulfide (Sigma-Aldrich), chloroform and acetone were used as received.
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3

Synthesis of Metal Xanthogenate Complexes

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Potassium ethyl xanthogenate (96%), antimony(III) chloride (SbCl3, ≥ 99.95%), copper(II) chloride dihydrate (CuCl2 2H2O, 99.99%), bismuth(III) chloride (BiCl3, ≥ 98%), Zinc(II) nitrate hexahydrate (Zn(NO3)2 6 H2O, ≥ 98%), methanol (99.8%), ethanol (95.0%), chloroform (CHCl3, ≥ 99%), Hexane (C6H14, ≥ 99%) were purchased from Sigma-Aldrich.
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4

Colloidal Nanocrystal Synthesis

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Antimony(III) chloride (99.999%, STREM),
copper(I) chloride (99.99%, Sigma-Aldrich), 1-dodecanethiol (DDT,
98%, Sigma-Aldrich), oleylamine (OLA, techn. 80–90%, Acros),
selenium (shots, 99.99%, STREM), chloroform (anhydrous, >99%, Sigma-Aldrich),
ethanol (anhydrous, 99.9%, Acros), tetrachloroethylene (anhydrous,
99%, Sigma-Aldrich), tetrabutylammonium iodide (TBAI, 99%, Sigma-Aldrich),
and methanol (anhydrous, 99.8%, Sigma-Aldrich) were used.
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5

Synthesis of Metal Complexes

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Methanol
(CH3OH, 99.8%), chloroform
(CHCl3, ≥99%), copper (II) chloride (CuCl2, ≥99.9%), antimony (III) chloride (SbCl3, ≥99.9%),
lead (II) acetate trihydrate (Pb(CH3CO2)2·3H2O, 99.9%), and sodium diethyldithiocarbamate
trihydrate ((C2H5)2NCSSNa·3H2O) were purchased from Sigma-Aldrich and used without further
purification.
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6

Antimony Sulfide Thin Film Synthesis

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Antimony(iii) chloride (SbCl3, 97%), thiourea (CH4N2S, 99% pure), 2-methoxy ethanol (C3H8O2, 98%), ethanol (C2H6O), acetone (C3H6O), and hydrochloric acid (HCl) were provided by Sigma-Aldrich company and employed as received without further treatment. The chemical reagents used for the synthesis were of analytical grade. Indium-doped tin oxide (ITO) conductive glass slides with surface resistivity of 10 Ω sq−1 and thickness of 2.2 mm were used as substrates for the deposition of Sb2S3 thin films.
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7

Antimony Detection Utilizing Carbon Nanofibres

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Analytical grade chemicals and ultrapure water were employed during the experiments. Antimony single standard (1000 mg L−1), ammonium pyrrolidine dithiocarbamate (APDC), iron (II) chloride tetrahydrate, carbon nanofibres (CNFs), hydrochloric acid, iron (III) chloride hexahydrate, ethanol, ammonia (25%), tetraethyl orthosilicate (TEOS), ethanol, 2-methoxy ethanol, antimony(III) chloride, styrene, ethylene glycol dimethacrylate (EGDMA), chloroform, 1,1′-azobisisobutyronitrile (AIBN) and nitric acid (65%) were obtained from Sigma-Aldrich (St. Louis, MO, USA).
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