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2 protocols using 1 butyl 3 methylimidazolium tetrafluoroborate

1

Perovskite Solar Cell Fabrication

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Zinc oxide dispersion,
tin chloride (SnCl2·2H2O) dehydrate, Al2O3 (aluminum oxide) NPs with <50 nm particle
size, magnesium acetate tetrahydrate [(CH3COO)2Mg·4H2O], lead(II) bromide (PbBr2), cesium iodide (CsI), tert-butylpyridine (TBP), Li bis(trifluoromethanesulfonyl)imide
(Li-TFSI), potassium hydroxide solution (KOH), and solvents dimethyl
sulfoxide (DMSO anhydrous, ≥99.9%), N,N-dimethylformamide (DMF anhydrous, 99.8%), diethyl ether
(99.0%), ethanol (99.8%), and 2-propanol anhydrous 99.5% were purchased
from Sigma-Aldrich. Tin(IV) oxide 15% in H2O colloidal
dispersion and 1-benzyl-3-methylimidazolium chloride (IL1) were purchased
from Alpha Aesar. 1-Butyl-3-methylimidazolium tetrafluoroborate (IL2)
was purchased from Acros Organics. Lead(II) iodide (PbI2) (99.99%, trace metal basis) was purchased from TCI Deutschland
GmbH. Formamidinium iodide (FAI) methylammonium bromide (MABr), and
methylammonium iodide (MAI) were purchased from GreatCell Solar. 18NR-T
titania paste and cobalt salt (III) FK209 TFSI (98%) were purchased
from Dyesol Limited. 2,2′,7,7′-Tetrakis-(N,N-di-p-methoxyphenylamine)-9,9′-spirobifluorene
(spiro-OMeTAD) (≥99.8%) was purchased from Borun New Material
Technology Co., Ltd.
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2

Perovskite Solar Cell Fabrication

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Dimethylformamide (DMF-anhydrous-Sigma-Aldrich),
dimethyl sulfide (DMSO-anhydrous-Sigma-Aldrich), toluene (anhydrous-Sigma-Aldrich),
chlorobenzene (CB-anhydrous-Sigma-Aldrich), dichlorobenzene (DCB-anhydrous-Sigma-Aldrich),
poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) (Solaris Chem),
MeO-2PACz (TCI), PFN-Br (Sigma-Aldrich), [6,6]-phenyl-C61-butyric
acid methyl ester (PCBM-99%-Solenne), bathocuproine (BCP-96%-Sigma-Aldrich),
SnOx ink (N30-Avantama), methylammonium bromide (MABr-99.99%-Greatcell
solar), formamidinium iodide (FAI-99.99%-Greatcell solar), cesium
iodide (CsI-99.99%-Sigma-Aldrich), lead bromide (PbBr2-TCI), lead
iodide (PbI2-TCI), 1-butyl-3-methylimidazolium tetrafluoroborate (BMITFB-98%-ACROS),
oleylamine (OAm-Sigma-Aldrich), and benzylhydrazine hydrochloride
(BHC-Life Chemicals) were purchased and used without further purification.
Glass/ITO substrates (10 Ω/sq) were purchased from Kin-Tec.
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