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4 protocols using sodium sulfide nonahydrate

1

Wool Extraction and Purification Protocol

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Sheep wool was commercially
obtained from a wool textile company (Uguuj-Shim LLC), Mongolia. Analytical
grade sodium sulfide nonahydrate (Na2S·9H2O), sodium hydroxide (NaOH), calcium oxide (CaO), hydrochloric acid
(HCl), and poly(vinyl alcohol) (PVA-124) with a hydrolyzation degree
of ≥97% were bought from Xilong Scientific Co., Ltd., China.
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2

Synthesis of Metal Complexes and Organic Compounds

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Cadmium nitrate tetrahydrate (Cd(NO3)2·4H2O), sodium sulfide nonahydrate (Na2S·9H2O) and potassium dichromate (K2Cr2O7) were provided by Xilong Scientific Co., Ltd (Guangdong, China). p-Nitrophenol (C6H5NO3), p-aminophenol (C6H6N2O2) and ammonium formate (CH5NO2) were supplied by Macklin Biochemical Co., Ltd (Shanghai, China). Attapulgite was purchased from Xuyi (Jiangsu, China). All the reagents were AR (analytical reagent) grade in purity. Deionized water used in all the processes was from local sources.
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3

Synthesis of Metal-Chalcogenide Thin Films

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Cadmium acetate dihydrate (Cd(CH3COO)2·2H2O, 98.0+%), sulfur powder (S, 99.5%), nickel acetate tetrahydrate (Ni(CH3COO)2·4H2O, 98.0+%), sodium hypophosphite monohydrate (NaH2PO2·H2O, 98.0–103.0%), lactic acid (C3H6O3, 85.0+%), and sodium sulfite anhydrous (Na2SO3, 97.0+%) were purchased from Sinopharm Chemical Reagent Co., Ltd (Shanghai, China). Thiourea (CH4N2S, 99.0+%) and sodium sulfide nonahydrate (Na2S·9H2O, 98.0+%) were bought from Xilong Scientific Co., Ltd (Shantou, China). Ethylenediamine (C2H8N2, 99.0+%) was purchased from Tianjin Fuchen Chemical Reagents (Tianjin, China). All chemicals were used as received without further purification.
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4

Synthesis of ZnS-MoS2 Heterostructure

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Conductive fluorine-doped tin oxide (FTO) glass substrates (KVFTO-P003) were purchased from Zhuhai Kaivo Optoelectronic Technology Co., Ltd (Guangdong, China). Diethyl zinc (Zn(C2H5)2, 99.999%) for atomic layer deposition (ALD) was bought from Ke-Micro Company (Jiaxing, China). Silver nitrate (AgNO3, 99.95%) was ordered from the First Reagent Factory (Shanghai, China). Methylene blue (MB, 98.5%), zinc acetate dihydrate (Zn(CH3COO)2·2H2O, 99%), sodium sulfide nonahydrate (Na2S·9H2O, 98%), isopropanol (IPA, 99.7%), and ammonium oxalate (AO, 99.5%), and hexamethylenetetramine(C6H12N4, 99.5%) were all bought from Xilong Chemical Co. Ltd (Guangdong, China). Octylamine (99%) was ordered from Jizhi Biochemical Technology Co., Ltd (Shanghai, China). Molybdenum trioxide (MoO3, 99.99%) was purchased from Xiamen Senkesi Technology Co., Ltd. Benzoquinone (BQ, 97%) was ordered from Aladdin Co. Ltd (Shanghai, China). Sulfur powder (99.99%) was bought from Xiamen Luyin Reagent Co., Ltd. Distilled water (H2O) with a resistivity higher than 18.0 MΩ cm was supplied by a Hi-tech laboratory water purification system. All the solvents and chemicals used in the experiments were at least reagent grade and were used as received.
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