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Cesium acetate

Manufactured by Merck Group
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Cesium acetate is a chemical compound that is commonly used as a laboratory reagent. It is a white, crystalline solid that is soluble in water and certain organic solvents. Cesium acetate has a variety of applications in scientific research and analysis, but its core function is to serve as a source of cesium ions for various chemical reactions and analytical techniques.

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Lab products found in correlation

Oleic acid, by Merck Group (7 mentions) 1 octadecene, by Merck Group (5 mentions) Oleylamine, by Merck Group (5 mentions) Hexane, by Merck Group (4 mentions) Sodium acetate, by Merck Group (3 mentions) Ethyl acetate, by Merck Group (3 mentions) Sodium borohydride, by Merck Group (2 mentions) Silver nitrate, by Merck Group (2 mentions) Bismuth iii acetate, by Merck Group (2 mentions) Potassium acetate, by Merck Group (2 mentions) Lithium acetate, by Merck Group (2 mentions) Benzoyl chloride, by Merck Group (2 mentions) Copper 1 acetate, by Merck Group (2 mentions) Zinc acetate, by Merck Group (2 mentions) Sodium borodeuteride, by Merck Group (2 mentions) Lead bromide, by Merck Group (2 mentions) Sodium hydroxide (naoh), by Merck Group (2 mentions) Dimethyl sulfoxide (dmso), by Merck Group (2 mentions) Absolute ethanol, by Thermo Fisher Scientific (1 mentions) Hydroiodic acid, by Merck Group (1 mentions)

15 protocols using cesium acetate

1

Synthesis of Cesium-based Nanocrystals

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Cesium acetate (CsOAc, 99.9%), 1-octadecene (ODE, 90%), hydrobromic acid (48% wt.), hydrochloric acid (37% wt.), hydroiodic acid (57% wt.) and hexane were purchased from Sigma Aldrich (Madrid, Spain). Oleic acid (OLA, 90%) and iodine (>99.5%) were bought from Fluka (Bucharest, Romania), while oleylamine (80–90% C18) was produced by Acros Organics (New Jersey, USA). Absolute ethanol, ethyl acetate (p.A.) and toluene (p.A.) were purchased from Fisher Scientific (Madrid, Spain).
Shaw P.J., Meyns M., Zuo Y., Grau-Carbonell A., Lagoudakis P.G., Charlton M.D., Martí-Sánchez S., Arbiol J., Cabot A, & Kanaras A.G. (2018). Colloidal Synthesis of CsX Nanocrystals (X = Cl, Br, I). Nanomaterials, 8(7), 506.
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2

Synthesis of Silver Nanoparticles

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All reagents were purchased from Sigma-Aldrich and used without further purification: silver nitrate (AgNO3, 99%, metal basis), triphenylphosphine (PPh3, 99%), 1,3-benzene dithiol (SSR, 99%), sodium borohydride (NaBH4, 99.9%), cesium acetate (CH3COOCs, 99%), methylene chloride (CH2Cl2, HPLC, Sigma-Aldrich), methanol (CH3OH, HPLC, Sigma-Aldrich), N, N-dimethylformamide (DMF, HPLC, Sigma-Aldrich), N-methyl-2-pyrrolidone (NMP, HPLC, Sigma-Aldrich), tetramethylene sulfone (TMS, HPLC, Sigma-Aldrich), and ethyl ether ((C2H5)2O, HPLC, Sigma-Aldrich).
Wei X., Kang X., Zuo Z., Song F., Wang S, & Zhu M. (2020). Hierarchical structural complexity in atomically precise nanocluster frameworks. National Science Review, 8(3), nwaa077.
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3

Synthesis of Colloidal Nanocrystals

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Cesium acetate (Cs(OAc), 99.99%; Sigma-Aldrich, Tokyo, Japan), sodium acetate (Na(OAc), 99.995%; Sigma-Aldrich, Tokyo, Japan), indium acetate (In(OAc)3, 99.99%; Sigma-Aldrich, Tokyo, Japan), antimony acetate (Sb(OAc)3, 99.99%; Sigma-Aldrich, Tokyo, Japan), germanium (IV) chloride (GeCl4, 99.99%; FUJIFILM Wako Chemicals, Osaka, Japan), 1-octadecene (ODE, 90%; Sigma-Aldrich, Tokyo, Japan), oleic acid (OA, 90%; Sigma-Aldrich, Tokyo, Japan), oleylamine (OAm, 70%; Sigma-Aldrich, Tokyo, Japan), chlorobenzene (C6H5Cl, 99.0%; FUJIFILM Wako Chemicals, Osaka, Japan), hexane (C6H14, 96.0%; FUJIFILM Wako Chemicals, Osaka, Japan) were used as received without further purification.
Tosa K., Ding C., Chen S., Hayase S, & Shen Q. (2024). Classifying the Role of Surface Ligands on the Passivation and Stability of Cs2NaInCl6 Double Perovskite Quantum Dots. Nanomaterials, 14(4), 376.
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4

Synthesis of Inorganic Nanoparticles

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Lead(II) acetate trihydrate (99.999%, Sigma-Aldrich),
cesium acetate (99.99%, Sigma-Aldrich), benzoyl chloride (Bz-Cl, 99%,
Sigma-Aldrich), benzoyl bromide (Bz-Br, 97%, Sigma-Aldrich), sodium
iodide (99.5%, Sigma-Aldrich), decane (anhydrous, ≥99%, Sigma-Aldrich),
oleylamine (technical grade, 70%, Sigma-Aldrich), oleic acid (technical
grade, 90%, Sigma-Aldrich), octylamine (99%, Sigma-Aldrich), erucic
acid (analytical standard, ≥99.0%, Sigma-Aldrich Supelco),
hexane (puriss. p.a., ACS reagent, Sigma-Aldrich), ethyl acetate (puriss.
p.a., ACS reagent, Sigma-Aldrich). All chemicals were used without
further purification.
Toso S., Baranov D., Giannini C, & Manna L. (2021). Structure and Surface Passivation of Ultrathin Cesium Lead Halide Nanoplatelets Revealed by Multilayer Diffraction. ACS Nano, 15(12), 20341-20352.
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5

Ion Channel Modulation Assay

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Nifedipine, NA, tetraethylammonium chloride (TEA), ACH, pyrazole-3 (Pyr3), bovine serum albumin (BSA), papain, collagenase H, dithiothreitol (DTT), dithioerythritol (DTE), cesium acetate, cesium chloride (CsCl), Mg-ATP, and agarose were purchased from Sigma (St. Louis, MO, USA). Nifedipine and Pyr3 were dissolved in dimethyl sulfoxide (DMSO), and other compounds were dissolved in the appropriate solutions used in the experiments.
Luo X., Xue L., Xu H., Zhao Q.Y., Wang Q., She Y.S., Zang D.A., Shen J., Peng Y.B., Zhao P., Yu M.F., Chen W., Ma L.Q., Chen S., Chen S., Fu X., Hu S., Nie X., Shen C., Zou C., Qin G., Dai J., Ji G., Su Y., Hu S., Chen J, & Liu Q.H. (2018). Polygonum aviculare L. extract and quercetin attenuate contraction in airway smooth muscle. Scientific Reports, 8, 3114.
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6

Synthesis of Colloidal Nanocrystals

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All the reagents were used without further purification. Cesium acetate (CsOAc, 99.99%), silver acetate (AgOAc, 99%), sodium acetate (NaOAc, 99.99%), indium(iii) acetate (In(OAc)3, 99.99%), bismuth(iii) acetate (Bi(OAc)3, 99.99%), chlorotrimethylsilane (TMSCl, 98%), oleic acid (OA, 90%), and 1-octadecane (ODE, 95%) were purchased from Sigma-Aldrich. Oleylamine (OAm, 80–90%) was purchased from Kanto Kagaku. Toluene (99.5%), hexane (96%), and ethyl acetate (99.5%) were purchased from Wako Chemicals.
Huang X., Matsushita Y., Sun H.T, & Shirahata N. (2022). Impact of bismuth-doping on enhanced radiative recombination in lead-free double-perovskite nanocrystals. Nanoscale Advances, 4(14), 3091-3100.
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7

Platinum Catalyst Preparation and Characterization

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Platinum on aluminum oxide was purchased from Alfa Aesar (LOT: F02R004, precise platinum content=4.86 wt %). Lithium acetate, potassium acetate, cesium acetate, potassium hydrogen carbonate, and potassium carbonate were obtained from Sigma Aldrich with a purity of 99.99 % and dried prior to use/weighing (120 °C, vacuum, at least 2 h). Lithium hydroxide (Merck, >98 %), sodium hydroxide (Merck, >99 %), potassium hydroxide (Merck, >85 %, rest H2O, K2CO3<1 %), and cesium hydroxide (Fluka, 95 %, rest H2O) were used as stock solution, the amount of hydroxide was determined by titration with 1 m HCl (Merck).
Kusche M., Agel F., Ní Bhriain N., Kaftan A., Laurin M., Libuda J, & Wasserscheid P. (2014). Methanol Steam Reforming Promoted by Molten Salt-Modified Platinum on Alumina Catalysts. Chemsuschem, 7(9), 2516-2526.
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8

Steroid Analysis with Alkali Acetates

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Polyalanine, testosterone, androsterone, α-estradiol, β-estradiol, epiandrosterone, cortisone, corticosterone, 11-deoxycortisol, lithium acetate, sodium acetate, potassium acetate, rubidium acetate, cesium acetate, and water were purchased from Sigma-Aldrich (St. Louis, MO, USA). Aldosterone, dehydroepiandrosterone (DHEA), methanol, and acetonitrile were purchased from Fisher Scientific (Pittsburg, PA, USA). Polyalanine was prepared at 12.5 μg/mL in 50% acetonitrile and 0.1% formic acid. Steroid solutions contained 50 μM of the given steroid and 100–150 μM of lithium acetate, sodium acetate, potassium acetate, rubidium acetate, or cesium acetate.
Rister A.L., Martin T.L, & Dodds E.D. (2018). Application of Group I Metal Adduction to the Separation of Steroids by Traveling Wave Ion Mobility Spectrometry. Journal of the American Society for Mass Spectrometry, 30(2), 248-255.
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9

Colloidal Nanocrystal Synthesis Protocol

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Zinc acetate (Zn(ac)2, 99.99%),
cesium acetate (Cs(ac), 99.99%), copper(I) acetate (Cu(ac), 97%),
manganese acetate (Mn(ac)2, 98%), 1-octadecene (ODE, 90%),
oleylamine (OLAM, 98%), oleic acid (OA, 90%), hexane (anhydrous, 95%),
ethyl acetate (99.9%), and benzoyl chloride (Bz-Cl, 98%) were purchased
from Sigma-Aldrich. All chemicals were used without any further purification.
Liu Y., Zaffalon M.L., Zito J., Cova F., Moro F., Fanciulli M., Zhu D., Toso S., Xia Z., Infante I., De Trizio L., Brovelli S, & Manna L. (2022). Cu+ → Mn2+ Energy Transfer in Cu, Mn Coalloyed Cs3ZnCl5 Colloidal Nanocrystals. Chemistry of Materials, 34(19), 8603-8612.
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10

Synthesis of Metal Nanoparticles

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Cesium
acetate (Cs(ac), 99.99%), zinc acetate
(Zn(ac)2, 99.99%), copper(I) acetate (Cu(ac), 97%), 1-octadecene
(ODE, 90%), oleylamine (OLAM, 98%), oleic acid (OA, 90%), benzoyl
chloride (Bz-Cl, 98%), hexane (anhydrous, 95%), and ethyl acetate
(99.9%) were purchased from Sigma-Aldrich. All chemicals were used
without any further purification.
Zhu D., Zaffalon M.L., Pinchetti V., Brescia R., Moro F., Fasoli M., Fanciulli M., Tang A., Infante I., De Trizio L., Brovelli S, & Manna L. (2020). Bright Blue Emitting Cu-Doped Cs2ZnCl4 Colloidal Nanocrystals. Chemistry of Materials, 32(13), 5897-5903.
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