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Trioctylphosphine top

Manufactured by Merck Group
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Trioctylphosphine (TOP) is a specialty chemical compound used in various laboratory applications. It is a clear, colorless liquid with a high boiling point. TOP serves as a coordinating ligand and is commonly used in the synthesis of semiconductor nanocrystals and other nanomaterials.

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Lab products found in correlation

Oleylamine, by Merck Group (5 mentions) 1 octadecene ode, by Merck Group (3 mentions) Oleic acid, by Merck Group (3 mentions) Sulfur, by Merck Group (2 mentions) Cadmium oxide, by Merck Group (2 mentions) Selenium se, by Merck Group (2 mentions) Selenium, by Merck Group (2 mentions) Thiourea, by Merck Group (1 mentions) Tellurium powder, by Merck Group (1 mentions) Stearic acid, by Merck Group (1 mentions) Cdso4, by Merck Group (1 mentions) Tris trimethylsilyl phosphine, by Strem Chemicals (1 mentions) Palmitic acid pa, by Tokyo Chemical Industry (1 mentions) Zn ac 2, by Merck Group (1 mentions) Butylamine, by Merck Group (1 mentions) Oleic acid oa, by Merck Group (1 mentions) Hexane, by Thermo Fisher Scientific (1 mentions) Cadmium acetate dihydrate, by Merck Group (1 mentions) Copper chloride dihydrate, by Merck Group (1 mentions) Myristic acid, by Merck Group (1 mentions)

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Trioctylphosphine (113 citations)

9 protocols using trioctylphosphine top

1

Synthesis of Colloidal Nanocrystals

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Tellurium powder (99.99%), copper(II) acetylacetonate (Cu(acac)2) (99.99+%), CuCl (99.99+%), Indium(III) acetylacetonate (In(acac)3) (99.99+%), stearic acid (98.5+%), trioctylphosphine (TOP) (97%), 1-octadecene (ODE) (90%), and CdSO4 (99.999%) were received from Aldrich Chemical Co. (Milwaukee, United States); Oleylamine (OLA) from TCI America (Portland, United States); ethanol (absolute), toluene (99.99%), and ammonium hydroxide (18 M NH3; ACS certified) from Fisher Scientific (Waltham, United States); and thiourea (>99.0%) from Sigma-Aldrich (St. Louis, United States). Oleylamine was degassed overnight at 110 °C under vacuum. All other chemicals were used without additional purification.
Jia G., Liu B., Wang K., Wang C., Yang P., Liu J., Zhang W., Li R., Zhang S, & Du J. (2019). CuInTe2 Nanocrystals: Shape and Size Control, Formation Mechanism and Application, and Use as Photovoltaics. Nanomaterials, 9(3), 409.
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2

Synthesis and Characterization of Colloidal Quantum Dots

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Indium(iii) acetate [In(Ac)3, 99.99%, Aldrich], zinc acetate [Zn(Ac)2, 99.99%, Aldrich], zinc oxide (ZnO, 99.999%, Aldrich), 1-octadecene (ODE, 90%, Aldrich), sulfur (99.98%, Aldrich), butylamine (99.5%, Aldrich), N,N-dimethylformamide (DMF, anhydrous, 99.8%, Aldrich) oleic acid (OA, 90%, Aldrich), trioctylphosphine (TOP, 97%, Aldrich), 1-dodecanethiol (DDT, >98%, Aldrich), tris(trimethylsilyl)-phosphine [(TMS)3P, 98% Strem Chemicals], palmitic acid (PA, 98%, Tokyo Chemical Industry), n-octylamine (OAm, 98%, Tokyo Chemical Industry), 6-mercapto-1-hexanol (MCH, 97%, Aldrich), and aluminium-doped zinc oxide ink (conductivity: 10−3–10−4 S cm−1, viscosity < 4 mPa s, Aldrich) were used without further purification. Aluminium (Al) wires were purchased from the Nilaco Corporation (Japan). The purity of argon gas was 99.999%. Using an oil rotary vacuum pump, the vacuum conditions of less than 60 Pa were used for degassing and argon gas purge.
Nemoto K., Watanabe J., Yamada H., Sun H.T, & Shirahata N. (2023). Impact of coherent core/shell architecture on fast response in InP-based quantum dot photodiodes. Nanoscale Advances, 5(3), 907-915.
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3

Synthesis of Nanocrystalline Materials

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Cadmium acetate dihydrate (Sigma-Aldrich,
98%), myristic acid (Sigma-Aldrich, 98%), selenium (Se, Sigma-Aldrich,
99.99%), tellurium (Te, SigmaAldrich, 99.99%), copper chloride dihydrate
(ACS reagent, 99.8%), zinc acetate trihydrate (Zn(CH3COO)2·2H2O, Sigma-Aldrich, 98%), sodium borohydride
(NaBH4, Sigma-Aldrich, 96%), trioctylphosphine (TOP, Sigma-Aldrich,
technical grade, 90%), 1-octadecene (ODE, Sigma-Aldrich, technical
grade, 90%), oleylamine (technical grade, 70%), sulfur (S, Sigma-Aldrich,
<99.5%), oleic acid (technical grade, Sigma-Aldrich, 90%), cadmium
oxide (Sigma-Aldrich, 99.9%), and lead oxide (Alfa Aesar, 99.9%).
Hexane (AR grade, 99%), 1,4-butanediol (90%, AR), dextrose (95% anhydrous,
AR), HCl (99%), and HNO3 (98%) were purchased from SD Fine
Chemicals. All chemicals were used without further purification.
Mahadevu R, & Pandey A. (2018). Thermodynamic Model for Quantum Dot Assemblies Formed Because of Charge Transfer. ACS Omega, 3(1), 266-272.
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4

Synthesis of Colloidal Nanocrystals

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Copper(i) acetate (CuOAc) (97%), gallium acetylacetonate (Ga(acac)3) (99.99%), 1-dodecanethiol (1-DDT) (98%), trioctylphosphine (TOP) (90%), indium(iii) acetate (In(OAc)3) (99.99%), selenium (99.99%), and octadecene (90%) were obtained from Sigma Aldrich. All chemicals were used as received.
Keating L, & Shim M. (2021). Mechanism of morphology variations in colloidal CuGaS2 nanorods. Nanoscale Advances, 3(18), 5322-5331.
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5

Quantum Dot Synthesis and Functionalization

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For QD synthesis, 99.95% Cadmium Oxide (CdO, Alfa Aesar), 99.99% Zinc Acetate (ZnAc, Sigma-Aldrich), and 99.99% Indium Acetate (InAc, ACROS Organics) were used for making cation precursors while 99.99% Selenium (Se, pellets, Sigma-Aldrich) and 99.5% Sulfur (S, ACROS Organics) were used for anion precursors. Octadecence (Tech, 90% ODE, Sigma-Aldrich), oleic acid (Tech, 90% OA, Sigma-Aldrich), oleylamine (Tech, 70% Olam, Sigma-Aldrich), 97% trioctylphosphine (TOP, Sigma-Aldrich), and trioctylphosphine oxide (TOPO, Sigma-Aldrich) were used as solvents and coordinating ligands during synthesis. Quantum dots were cleaned and stored in organic solutions post-synthesis using hexane (Sigma-Aldrich), chloroform (CHCl3, J.T.Baker), ethanol (EtOH, anhydrous, Sigma-Aldrich), and methanol (MeOH, Sigma-Aldrich). For CL4 synthesis, alpha-lipoic acid (LA, Sigma Aldrich), 97% N,N’-Carbonyldiimidazole (CDI, Alfa Aesar), ethylenediamine (EDA Sigma-Aldrich), methyl acrylate (ACROS Organics), lithium hydroxide (LiOH, Sigma-Aldrich) and sodium borohydride (NaBH4, ACROS Organics) were used. Zinc nitrate hexahydrate, (reagent grade, 98%, Sigma Aldrich) was used for metalated ligand transfer. Buffered solutions were prepared by using phosphate buffered saline packets (pH 7.4, Sigma-Aldrich), sodium citrate dihydrate (Sigma-Aldrich) and citric acid (Fisher Chemicals).
Chern M., Toufanian R, & Dennis A.M. (2020). Quantum Dot to Quantum Dot Förster Resonance Energy Transfer: Engineering Materials for Visual Color Change Sensing. The Analyst, 145(17), 5754-5767.
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6

Synthesis of Semiconductor Nanocrystals

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Polyacrylonitrile (PAN, Mw = 150 000) was purchased from Sigma Aldrich (USA). N,N-Dimethylformamide (DMF) was purchased from Sigma Aldrich (USA). CdO (99.9%), oleic acid (OA, 90%), 1-octadecene (1-ODE, 90%), trioctylphosphine (TOP, 97%), and Se powder (99.99%) were purchased from Sigma Aldrich. PbO (99.99%), bis(trimethylsilyl)sulfide ((TMS)2S, synthesis grade), InCl3 (98%), ZnCl2 (97%), oleylamine (70%), tris(dimethylamino)phosphine (P(DMA)3, 97%), 1-dodecanethiol (DDT, 98%), CuI (99.999%), indium acetate (99.99%), zinc acetate (99.99%), sulfur (99.998%), zinc diethyldithiocarbamate (Zn DDTC, 97%), cadmium acetate (99.995%), ZnO (99.999%), sodium sulfide nonahydrate (98+%), and sodium sulfite (≥98%) were purchased from Sigma Aldrich.
Song T., Cheong J.Y., Choi J.Y., Park C., Lee C., Lee C., Lee H.M., Choi S.Y., Song H., Kim I.D, & Jeon D.Y. (2019). A feasible strategy to prepare quantum dot-incorporated carbon nanofibers as free-standing platforms. Nanoscale Advances, 1(10), 3948-3956.
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7

Synthesis of CoPd Nanoparticles

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Oleylamine (80–90%, Sigma-Aldrich) was distilled under vacuum twice before the reaction. CoPd NPs were synthesized by a modified synthetic procedure which was reported by Mazumder et al. (2012 (link)). 20 mL of Oleylamine were loaded in a three-neck flask and the solution degassed at 403 K for 2 h under the flow of argon. After cooling down to the room temperature, 0.30 mmol of palladium bromide (PdBr2, 99.0 wt%, Sigma-Aldrich) and 0.20 mmol of cobalt acetate (Co(ac)2, 99.995 wt%, Sigma-Aldrich) were added to the solution. The flask was enclosed and quickly heated under the argon flow to 333 K. After reaching this temperature, 0.5 mL of trioctylphosphine (TOP, 97 wt%, Sigma-Aldrich) was added to the solution. The temperature was increased to 533 K and heated for 2 h. Subsequently, the mixture was cooled down to 323 K and the NPs were precipitated with 25 mL of ethanol (absolute, 99.95% Chemsolute GmbH). The CoPd NPs were centrifuged at 12.000 rpm for 20 min, redispersed in hexane and washed twice with 25 mL of ethanol.
Yakymovych A., Slabon A., Plevachuk Y., Sklyarchuk V, & Sokoliuk B. (2018). Lightweight magnesium nanocomposites: electrical conductivity of liquid magnesium doped by CoPd nanoparticles. Applied Nanoscience, 9(5), 1119-1125.
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8

Synthesis of Colloidal Quantum Dots

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All materials are commercially available, and were used as received. Gallium acetylacetonate (Ga(acac)3) was purchased from Strem Chemicals (Newburyport, MA, USA). Cadmium oxide, selenium, 1-octadecene, trioctylphosphine (TOP), oleylamine, oleic acid, thioglycolic acid (TGA), trioctylphospine oxide (TOPO), tetradecylphosphonic acid, and tetrahydrofuran (THF) were all purchased from Sigma Aldrich (St. Louis, MO, USA).
Stanish P.C, & Radovanovic P.V. (2016). Energy Transfer between Conjugated Colloidal Ga2O3 and CdSe/CdS Core/Shell Nanocrystals for White Light Emitting Applications. Nanomaterials, 6(2), 32.
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9

CdSe/CdS Nanorods and Gold Nanoparticles Synthesis

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For CdSe/CdS NRds: Cadmium oxide (CdO) (Sigma Aldrich 99.99%), sulfur powder (S, Afla Aesar, 99.5%), selenium powder (Strem Chemicals, 99.99%), Trioctylphosphine oxide (TOPO 99%), trioctylphosphine (TOP, Sigma-Aldrich, 97%), Octadecylphosphonic acid (ODPA, TCI 99%), hexylphosphonic acid -(HPA, TCI 99%), Chloroform (Carlo Erba), ethanol absolute anhydrous (Carlo Erba, 99.9%), methanol (Carlo Erba, 99.8%), acetone (Carlo Erba, 99.8%), n-hexane (Carlo Erba), n-octane (SDS, 99%), toluene (Carlo Erba, 99.3%) and n-octane (SDS, 99%). For Gold NPs: Chlorotriphenylphosphine gold ÄšI) and tertbutylamine borane (STEM chemicals), Dodecanethiol (Sigma-Aldrich), toluene ( Riedel de Haen,98%) and ethanol (Prolabo,99.8%). All reagents were used as received without further purification.
Jeridi H., Niyonzima J.D., Sakr C., Missaoui A., Shahini S., Vlad A., Coati A., Goubet N., Royer S., Vickridge I., Goldmann M., Constantin D., Garreau Y., Babonneau D., Croset B., Gallas B., Lhuillier E, & Lacaze E. (2022). Unique orientation of 1D and 2D nanoparticle assemblies confined in smectic topological defects. Soft matter, 18(25).
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