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Copper 1 acetate

Manufactured by Merck Group
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Copper(I) acetate is a chemical compound with the formula Cu(CH3COO). It is a white or pale blue crystalline solid that is used as a laboratory reagent and in various industrial applications.

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Lab products found in correlation

Oleylamine, by Merck Group (9 mentions) Oleic acid, by Merck Group (7 mentions) 1 octadecene, by Merck Group (6 mentions) 1 dodecanethiol, by Merck Group (3 mentions) Zinc acetate, by Merck Group (3 mentions) Trioctylphosphine, by Merck Group (3 mentions) Hexane, by Merck Group (3 mentions) Trifluoroacetic acid tfa, by Merck Group (2 mentions) Copper 1 iodide, by Merck Group (2 mentions) Cesium acetate, by Merck Group (2 mentions) Benzoyl chloride, by Merck Group (2 mentions) Ethyl acetate, by Merck Group (2 mentions) Methanol, by Merck Group (2 mentions) Nitric acid, by Merck Group (2 mentions) Anhydrous toluene, by Merck Group (2 mentions) Trioctylamine, by Merck Group (2 mentions) Ethanol, by Merck Group (2 mentions) Copper 1 bromide, by Merck Group (2 mentions) Copper 1 chloride, by Merck Group (2 mentions) Magnesium chloride, by Thermo Fisher Scientific (1 mentions)

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Copper acetate (24 citations)

13 protocols using copper 1 acetate

1

Synthesis of Copper-based Nanomaterials

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Copper (I) chloride (99.99%, STREM), Oleylamine (Oam, 95%, STREM), Oleic acid (OA, 90%, Aldrich), Octadecene (ODE, 90%, Sigma-Aldrich), Copper (I) acetate (ABCR), Copper (II) acetylacetonate (97%, Sigma-Aldrich), TOPO (Strem, 99%), chlorobenzene (anhydrous, 99.8%, Sigma-Aldrich), Sulfur (99.998%, Sigma-Aldrich), 1-dodecanethiol (98%, Sigma Aldrich), Toluene (99.9%, Sigma-Aldrich), Ethanol (Fluka), Hydrazine (Gerling Holz+Co), Acetonitrile (ACN, max. 0.005% H2O, Merck), Copper (II) sulfide (CuS, 99.5%, STREM), Copper (I) sulfide (Cu2S, 99.5%, Alfa Aesar), Magnesium-bis(hexamethyldisilazide (Mg(HMDS)2, 97%, Sigma-Aldrich), Magnesium bis(trifluoromethanesulfonyl)imide (Mg(TFSI)2, 99.5%, Solvionic), Magnesium chloride (MgCl2, 99.9%, Alfa Aesar), Tetraglyme (99%, ABCR).
Kravchyk K.V., Widmer R., Erni R., Dubey R.J., Krumeich F., Kovalenko M.V, & Bodnarchuk M.I. (2019). Copper sulfide nanoparticles as high-performance cathode materials for Mg-ion batteries. Scientific Reports, 9, 7988.
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2

Fmoc-based Peptide Synthesis Workflow

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Fmoc (9-fluorenyl methoxycarbonyl)–protected amino acids including Fmoc-propargyl glycine, N,N,N′,N′-tetramethyl-O-(1H-benzotriazol-1-yl) uronium hexafluorophosphate, and piperidine for SPPS were purchased from AAPPTEC Inc. (Louisville, KY). Rink amide polystyrene resin for SPPS was purchased from CEM Corporation (Matthews, NC). HPLC-grade acetonitrile (ACN) and dimethylformamide (DMF) was purchased from Thermo Fisher Scientific (Fairlawn, NJ). Copper (I) acetate, 4-azidobutanoic acid, trifluoroacetic acid (TFA), triisopropylsilane (TIS), triethylamine, anhydrous DMF, anhydrous dimethyl sulfoxide (DMSO), diisopropylethylamine, ethyl cyanohydroxyiminoacetate (Oxyma), and diisopropylcarbodiimide (DIC) were purchased from Sigma-Aldrich (St. Louis, MO).
Qin J., Sloppy J.D, & Kiick K.L. (2020). Fine structural tuning of the assembly of ECM peptide conjugates via slight sequence modifications. Science Advances, 6(41), eabd3033.
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3

Synthesis and Characterization of Quantum Dots

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Copper (I) acetate (97 %), zinc acetate (99 %), oleic acid (90 %), oleylamine (70 %), 1-octadecene (ODE, 90 %), poly(maleic anhydride-alt-1-octadecene) (PMAO) (average Mn 30,000–50,000 as a powder), 3-(dimethylamino)-1-propylamine (DMAPA) (99 %), methyl iodide (99 %), poly-D-lysine, and gelatin were purchased from Sigma-Aldrich. Indium (III) acetate (99.99 %) and 1-dodecanethiol (DDT, 98 %) were purchased from Alfa Aesar. RPMI-1640 and MEM media were from Corning Cellgro. Heat-inactivated fetal bovine serum(FBS) was from Gibco. Fluorescein diacetate/propidium iodide (FDA/PI) was from Invitrogen. Dulbecco’s phosphate-buffered saline (DPBS) was from Fisher Scientific. U-87 MG and HEK-293 cells were ordered from ATCC. Chemicals were used as received without further purification.
The ultraviolet and visible (UV–Vis) spectra of QDs in organic solvents and aqueous solutions were obtained with a UV–Vis spectrometer (UV-2450 from Shimadzu) using cuvettes with a path length of 1 cm. Photoluminescence spectra were acquired using a spectrophotometer (RF-5301PC from Shimadzu). Infrared (IR) spectra of polymers and QDs were collected using a FT-IR spectrometer (Perkin-Elmer Frontier) equipped with attenuated total reflectance and measurement software (Spectrum 10). Particle size measurements of QDs were made using a ZetaPALS dynamic light scattering detector (Brookhaven Instruments Corp.).
Huang L., Liao M., Chen S., Demillo V.G., Dupre S.A., Zhu X., Publicover N.G, & Hunter KW J.r. (2014). A polymer encapsulation approach to prepare zwitterion-like, biocompatible quantum dots with wide pH and ionic stability. Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology, 16(8), 2555.
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4

Synthesis of Copper Nanocrystals

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Copper(i) acetate (or CuOAc, 97%), trioctylphosphine ({CH3(CH2)7}3P, or TOP, 90%), oleic acid (C17H33CO2H or OLAC, 90%), oleylamine (C17H33NH2 or OLAM, 70%), 1-octadecene (C18H36 or ODE, 90%) were all purchased from Sigma-Aldrich and used as received.
Varandili S.B., Stoian D., Vavra J., Pankhurst J, & Buonsanti R. (2020). Ligand-mediated formation of Cu/metal oxide hybrid nanocrystals with tunable number of interfaces. Chemical Science, 11(48), 13094-13101.
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5

Colloidal Copper Sulfide Synthesis

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Copper(i) iodide (CuI, 99.5%), copper(i) acetate (CuOAc, 97%), oleylamine (OAm, 70%), sulfur powder (99.98%), tetrachloroethylene (TCE, spectroscopy grade Uvasol), and diphenylether (DPE, 99%) were purchased from Sigma-Aldrich; toluene (99.5%) and methanol (>99.9%) were purchased from VWR, and acetone (99%) was purchased from Th. Geyer. Chemicals were used as received without additional purification.
Lesyuk R., Klein E., Yaremchuk I, & Klinke C. (2018). Copper sulfide nanosheets with shape-tunable plasmonic properties in the NIR region †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8nr06738d. Nanoscale, 10(44), 20640-20651.
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6

Colloidal Nanocrystal Synthesis Protocol

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Zinc acetate (Zn(ac)2, 99.99%),
cesium acetate (Cs(ac), 99.99%), copper(I) acetate (Cu(ac), 97%),
manganese acetate (Mn(ac)2, 98%), 1-octadecene (ODE, 90%),
oleylamine (OLAM, 98%), oleic acid (OA, 90%), hexane (anhydrous, 95%),
ethyl acetate (99.9%), and benzoyl chloride (Bz-Cl, 98%) were purchased
from Sigma-Aldrich. All chemicals were used without any further purification.
Liu Y., Zaffalon M.L., Zito J., Cova F., Moro F., Fanciulli M., Zhu D., Toso S., Xia Z., Infante I., De Trizio L., Brovelli S, & Manna L. (2022). Cu+ → Mn2+ Energy Transfer in Cu, Mn Coalloyed Cs3ZnCl5 Colloidal Nanocrystals. Chemistry of Materials, 34(19), 8603-8612.
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7

Synthesis of Colloidal Quantum Dots

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Copper(I)
acetate (CuAc, 97%), indium acetate
(In(Ac)3, 99.99%), 1-dodecanethiol (DDT, ≥98%),
trioctylphosphine (TOP, 90%), trioctylphosphine oxide (TOPO, 99%),
1-octadecene (ODE, 90%), nitric acid (HNO3, 69.5%), anhydrous
toluene, methanol, and butanol were purchased from Sigma-Aldrich.
Multi-Element calibration standard 3 and Multi-Element calibration
standard 5 (10 μg/mL of each element) were purchased from PerkinElmer.
TOPO and ODE were degassed at 120 °C under vacuum overnight prior
to synthesis. Other reagents were used as received. The chemicals
were weighed and handled inside a glovebox.
Xia C., Wu W., Yu T., Xie X., van Oversteeg C., Gerritsen H.C, & de Mello Donega C. (2018). Size-Dependent Band-Gap and Molar Absorption Coefficients of Colloidal CuInS2 Quantum Dots. ACS Nano, 12(8), 8350-8361.
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8

Synthesis of Copper-Cerium Nanocrystals

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Cerium(III) nitrate hexahydrate (Ce(NO3)3·6H2O, 99% trace metals basis), copper(II) nitrate trihydrate (Cu(NO3)2·3H2O, purum p.a., 98.0–103% (RT)), copper(I) acetate (CuAc, 97%), oleylamine (technical grade, 70%), 1‐octadecene (technical grade, 90%), trioctylamine (98%), tetradecylphosphonic acid (TDPA, 98%), and white quartz (SiO2, ≥99.995%, trace metals basis) were purchased from Sigma‐Aldrich. Solvents, including hexane, ethanol, acetone, and chloroform were of analytical grade. All chemicals were used as received without further purification.
Sun Y., Polo‐Garzon F., Bao Z., Moon J., Huang Z., Chen H., Chen Z., Yang Z., Chi M., Wu Z., Liu J, & Dai S. (2022). Manipulating Copper Dispersion on Ceria for Enhanced Catalysis: A Nanocrystal‐Based Atom‐Trapping Strategy. Advanced Science, 9(8), 2104749.
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9

Synthesis of Metal Nanoparticles

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Cesium
acetate (Cs(ac), 99.99%), zinc acetate
(Zn(ac)2, 99.99%), copper(I) acetate (Cu(ac), 97%), 1-octadecene
(ODE, 90%), oleylamine (OLAM, 98%), oleic acid (OA, 90%), benzoyl
chloride (Bz-Cl, 98%), hexane (anhydrous, 95%), and ethyl acetate
(99.9%) were purchased from Sigma-Aldrich. All chemicals were used
without any further purification.
Zhu D., Zaffalon M.L., Pinchetti V., Brescia R., Moro F., Fasoli M., Fanciulli M., Tang A., Infante I., De Trizio L., Brovelli S, & Manna L. (2020). Bright Blue Emitting Cu-Doped Cs2ZnCl4 Colloidal Nanocrystals. Chemistry of Materials, 32(13), 5897-5903.
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10

Synthesis of Copper Nanostructures

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Indium nitrate hydrate
(In(NO3)3·xH2O, 99.9%), copper(I)
acetate (CuOAc, 97%), copper acetylacetonate (Cu(acac)2, 97%), copper(I) iodide (CuI, 98%), copper(I) bromide (CuBr, 98%),
copper(I) chloride (CuCl, 99%), 1-dodecanethiol (1-DDT, ≥98%),
oleic acid (OA, 90%), oleylamine (OLAM, 70%), anhydrous toluene, methanol,
butanol, and ethanol were purchased from Sigma-Aldrich and used as
received.
Xia C., van Oversteeg C.H., Bogaards V.C., Spanjersberg T.H., Visser N.L., Berends A.C., Meeldijk J.D., de Jongh P.E, & de Mello Donega C. (2021). Synthesis and Formation Mechanism of Colloidal Janus-Type Cu2–xS/CuInS2 Heteronanorods via Seeded Injection. ACS Nano, 15(6), 9987-9999.
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