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3 protocols using ferrocene

1

Synthesis and Characterization of MWCNT Nanomaterials

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Chemicals including carboxylic MWCNTs (outer
diameter: 8–15 nm, length: 50 μm, 95%), 4-hydroxyaminobenzene
(98%), phenol (99%), diethylenetriamine (99%), SDS (99%), and 1,2-dibromoethane
(99%) were obtained from J&K Chemicals. 11-Bromoundecanoic acid
(95%) and PEI with a molecular weight of 10 000 were purchased
from Aladdin Industrial Corporation. PPE membrane (mean pore size
0.22 mm) was obtained from Xiya Reagent. Ferrocene (98%) and all other
analytical grade reagents including methanol, dichloromethane, hydrochloric
acid, sodium hydroxide, and FeCl3 were obtained from Sinopharm
Chemical Reagent Co, Ltd. All chemicals were used as received without
further purification. The surfactant FADETA was synthesized according
to the procedure as mentioned in Scheme S1 in the Supporting Information. Water was Millipore Milli-Q-grade.
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2

Synthesis of Functional Materials

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Ethylene glycol (purity
> 99%), ferrocene (purity > 98%), glucose (purity > 98%),
hydrogen
peroxide (H2O2, 30% water solution), glutathione
(reduced, purity > 98%), acetone (purity > 99%), glycine (purity
>98%), lysine (purity > 98%), acrylamide (AM, purity > 98%),
and urea
(purity > 98%) were purchased from Sinopharm. BSA (purity >96%) was
purchased from Aladdin. CBIS (purity > 99%), glutathione (purity
>98%), cysteine (purity > 98%), homocysteine (purity > 90%),
BIS (purity
> 99%), and 2-hydroxy-4′-(2-hydroxyethoxy)-2-methyl-propiophe
(purity > 98%) were purchased from Aldrich. The chemicals were
used
directly without further purification.
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3

Synthesis of MoO3 Composites

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MoO3 (99.5%) was purchased from Alfa Aesar (Yingong RD No. 229, Fengxian Chemical District, Shanghai, China), The other reagents were purchased from Sinopharm Chemical Reagent Co. Ltd. (Ningbo RD No. 22, Shanghai, China): Sulfur (99.999%), Ferrocene (98%), Ethanol (AR), HCl (37%, AR), and HNO3 (66%, AR). All chemical reagents have been purchased from company and used without further purification.
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