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2 protocols using 2 ethylhexyl methacrylate

1

Multicomponent Polymer Composite Synthesis

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Poly(4-styrenesulfonic acid-co-maleic acid, SS : MA = 3 : 1) sodium salt (PSSMA, MW = 20 000), styrene (St), tetraethyl orthosilicate (TEOS), silver nitrate (AgNO3), decane, TA, 4-NP, rhodamine B, MB, anhydrous sodium acetate (NaOAc), sodium 4-vinylbenzenesulfonate (NaSS), ethylene glycol (EG), ammonium hydroxide (NH4OH) solution, 2-ethylhexyl methacrylate (EHMA), 3-(trimethoxysilyl)propyl methacrylate (MPS), ferric chloride (FeCl3), isoamyl alcohol, ferric chloride hexahydrate (FeCl3·6H2O), and azobisisobutyronitrile (AIBN) were obtained from Sigma-Aldrich. All chemicals were used as received without further purification. Deionized (DI) water with a resistivity of 18.2 MΩ cm, purified by a water ultra-purification system (ROMAX, Human Science), was utilized for silica coating, preparation of organic dye solutions, and dispersion of particles.
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2

Synthesis and Characterization of Polymeric Microspheres

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The monomers 2-ethylhexyl acrylate (EHA; 98%) and 2-ethylhexyl methacrylate (EHMA; 98%), cross-linker ethylene glycol dimethacrylate (EGDMA; 98%), initiator sodium persulfate (NaPS; 98%), sodium chloride (NaCl; 99%), surfactants dimethyldioctadecylammonium bromide (DODAB; 98%) and Span 80, hydrochloric acid (HCl; 37%), and ciprofloxacin were purchased from Sigma-Aldrich and used as received. The alcohol 2-propanol (IPA; 99.5%) was obtained from Fisher Scientific. Superffin infiltration media was purchased from Source Medical Products. Fluoresbrite YO Carboxylate 0.50-μm microspheres and Fluoresbrite YG 25-μm microspheres were ordered from Polysciences, Inc. Polymeric microspheres (polystyrene divinyl benzene, diameter 1–15 μm) were obtained from Duke Scientific Corporation.
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