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3 protocols using 1 4 dioxane

1

Synthesis of Zirconium-based Nanomaterials

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Zirconium (IV) propoxide was obtained from the Tokyo Chemical Industry Co., Ltd. Qu was obtained from the Harbin Medical University Cancer Hospital. IL was provided by Shanghai Chengjie Chemical Co., Ltd (China). mPEG-SH was obtained from the Beijing Kaizheng United Medical Technology Co., Ltd. Copper sulfate pentahydrate (CuSO4·5H2O) was provided by Xiqiao Chemical Co., Dissolved oxygen reagents were purchased from the Beijing Anshengdacheng Electronics Co., Ltd. Ltd. 1,4-dioxane was provided by the Beijing Chemical Factory. Ammonia was obtained from the Sinopharm Group Chemical Reagent Co., Ltd. All the reagents used in the experiments were analytical grades, and they need not be further purified when used.
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2

Biopolymeric Scaffold Fabrication

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GE (type B, from cow hides, 110–130 Blooms) was purchased from Thermo Scientific (Waltham, MA, USA). HAp was obtained from J&K Scientific (Beijing, China). Glutaraldehyde (25% water solution) was purchased from Shantou Xilong Chemicals (Shantou, China). Sodium carbonate and 1,4-dioxane were obtained from Beijing Chemical Works (Beijing, China). Sodium chloride, potassium phosphate dibasic trihydrate, 4-(2-hydroxyethyl) piperazine-1-ethanesulfonic acid and calcium chloride (anhydrous) were purchased from Sigma–Aldrich (Saint Louis, MO, USA). Sodium bicarbonate, potassium chloride, magnesium chloride hexahydrate, sodium hydroxide, and sodium sulfate were obtained from Sinopharm Chemical Reagents (Shanghai, China).
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3

Synthesis and Characterization of MWCNTs

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MWCNTs (purity ≥ 95%; diameter 10–20 nm; length 0.5–500 μm) were provided from Shenzhen Nanotech. Sodium azide was purchased from Qixia Chemicals. Acryloyl chloride was obtained from Energy and Chemical Industry. Acetone (99.5%), ethanol (99.7%) and 1,4-dioxane were purchased from Beijing Chemical Factory. Sodium dodecyl benzene sulfonate (SDBS, 99%) was obtained from Sinopharm Chemical Reagents. Azobisisobutyronitrile (AIBN) was provided by Beijing Chemical Reagents. Paraformaldehyde (POM, 95%), melamine, n-pentane (99%), N,N-dimethylacetamide (DMAC, 99.8%), sodium polyphosphate (99%), emulsifier OP-10, monoethanolamine (MEA) and sodium formate (99.5%) were purchased from Fu Chen Chemical Reagent Factory. Anhydrous formic acid was provided by Tianjin Kwangfu Fine Chemical Industry Research Institute. Diglycidyl ether of bisphenol A (DGEBA) was purchased from Heli Resins with the epoxide equivalent weight of 196 g per equiv. epoxy. 1,6-Diaminohexane (DAH) was obtained from Shanghai Reagents and purified by distillation under reduced pressure prior to use.
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