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11 mercaptoundecyl trimethyl ammonium bromide

Manufactured by Merck Group
Sourced in Poland

(11-Mercaptoundecyl)trimethyl-ammonium bromide is a chemical compound used in laboratory settings. It serves as a surfactant and has applications in various research and analytical procedures. The specific core function of this product is to facilitate the preparation and analysis of samples in controlled environments.

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2 protocols using 11 mercaptoundecyl trimethyl ammonium bromide

1

Synthesis of J-Aggregates using Dye

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The chosen dye for this work was 5-Chloro-2-[3-[5-chloro-3-(4-sulfobutyl)-3H-benzothi-azol-2-ylidene]-propenyl]-3-(4-sulfobutyl)-benzothiazol-3-ium hydroxide, inner salt, triethylammonium salt (S2275 dye) and was purchased from FEW Chemicals (Wolfen, Sachsen-Anhalt, Germany). To form the J-aggregates, we used sodium chloride (NaCl) from Sigma Aldrich (St. Louis, MO, USA). For the particle stabilization, we used cetyltrimethylammonium bromide (CTAB), (11-Mercaptoundecyl)trimethyl-ammonium bromide (TMA), and poly(diallyldimethylammonium chloride) (PDDA) that were purchased from Sigma Aldrich and 11-Mercaptoundecane-1-sulfonic acid sodium salt (MUS) that was purchased from Prochimia (Gdynia, Poland). Borosilicate cover glass (thickness 0.13–0.16 mm) was used to prepare solid-state samples and was purchased from VWR International (Radnor, PA, USA).
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2

Synthesis of Gold Nanoparticles and Nanorods

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Sodium citrate tribasic dihydrate (ACS reagent, ≥99.0%), cetyltrimethylammonium bromide (CTAB, 99%), sodium borohydride (NaBH4, 99%), L-ascorbic acid (AA, >99%), silver nitrate (AgNO3, >99%), cysteamine hydrochloride (>99%), (11-Mercaptoundecyl)trimethylammonium bromide (TMA, >99%), hydrochloric acid (37%) and tetrachloroauric acid trihydrate (99.9%) were obtained from Sigma-Aldrich. Thiolfunctionalized methoxy-polyethylene glycol (mPEG-SH; MW=5000 Da) was supplied by RappPolymere GmbH. All chemicals were used as received. For all experiments, ultrapure water with a resistivity of 18.2 MΩ•cm was used. Spherical gold nanoparticles with a diameter of 19 nm were prepared using the traditional Turkevich method. 22 These particles were also used for the preparation of larger, 40 nm diameter particles by using modified seeded three-step growth method. 23 The nanorod samples (54x15 nm; 60x16 nm; 80x21 nm) were prepared according to previously published seedmediated protocol.
24
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