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2 protocols using 2 4 dichloroaniline

1

Volatile Standards Preparation and Characterization

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The volatile standards used in this study are shown in Additional File 4: Table S1. First, 2,4-dichloroaniline (99.5% purity) was purchased from Tokyo Chemical Industry Co., Ltd. (Tokyo, Japan) for the reagents. However, while n-heptyl β-D-glucopyranoside (98% purity) was purchased from Sigma-Aldrich, Inc. (St. Louis, MO, USA), dichloromethane (99.5% purity), liquid chromatography-mass spectrometry-grade methanol, citric acid, sodium phosphates, sodium fluoride (NaF), ascorbic acid, sodium hydroxide (NaOH) and 3-octanol (97% purity) were obtained from Wako Co. Ltd. (Osaka, Japan).
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2

Quantitative Analysis of Aniline Derivatives

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Sodium benzoate and sodium hydroxide solution were purchased from Kanto Chemical (Japan). Aniline, distilled water (HPLC grade), formic acid, acetonitrile (HPLC grade), tetrahydrofuran (stabilizer free, special grade), K2HPO4, KH2PO4, Na2HPO4·12H2O, NH4Cl, MgSO4·7H2O, CaCl2, FeCl3·6H2O, and 0.5% phosphate solution were purchased from FUJIFILM Wako Pure Chemical (Japan). Sodium acetate, benzyl alcohol, phenol, 2,4-dichloroAniline, 2,3-dichlorobenzoic acid, and tris(2-ethylhexyl) trimellitate (Tris) were purchased from Tokyo Chemical Industry (TCI, Japan).
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