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6 protocols using pdda solution

1

Preparation of PDDA-MWCNTs Dispersion

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PDDA-MWCNTs solution (1 g/L) was prepared by adding MWCNTs (1 mg) to PDDA solution (1 mL, 10 g/L; Sigma, SAINT LOUIS, MO, USA), followed by sonication for 60 min to form a homogenous dark solution, which was kept at room temperature for 24 h, filtered, and then stored at 4 °C until further use.
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2

Synthesis of PEDOT:PSS on Stainless Steel

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SUS316L stainless steel substrate was purchased from Sinkang Industries Co., Ltd., (New Taipei City, Taiwan). Graphite powder was purchased from Allightec Co., (Taichung City, Taiwan). 3,4-Ethylenedioxythiophene (EDOT), PSS solution (Mw 75,000 g/mol), hydrogen peroxide (H2O2), hydrochloric acid (HCl), sulfuric acid (H2SO4), nitric acid (HNO3), sodium chloride (NaCl), alcohol, potassium permanganate (KMnO4), and PDDA solution were purchased from Sigma-Aldrich Corp. (St. Louis, MO, USA) and Acors Organics (Ozaukee County, WI, USA).
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3

Fabrication of Flexible Electrochemical Devices

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Graphite powder, potassium permanganate, sulfuric acid, sodium nitrate, hydrogen peroxide, ammonium persulfate, aniline, PDDA solution, Nafion 117 solution, trichloro(1H,1H,2H,2H‐perfluorooctyl)silane, hydrochloric acid, and other chemicals were purchased from Sigma‐Aldrich (Buchs, Switzerland) and used as received. Polyimide films with a thickness of 125 µm were also purchased from Sigma‐Aldrich. Silver Flake Ink (Metalon HPS‐021LV) was purchased from Novacentrix (Austin, USA). Polymer aluminum capacitors were purchased from Mouser Electronics (Munich, Germany). The Joy‐it SBC‐LCD 16 × 2 display module (HD44780) (cat. no. 1 503 825), L10 Solar Garden Light (0.2 W, SMD LEDs; cat no. 2 497 614), and Philips GU5.3 12 V/3.5 W/200 lumen LEDspot Light (Philips) were purchased from Conrad Electronics AG (Wollerau, Switzerland). The rechargeable lithium polymer battery (3.7 V/600 mAh) was purchased from RS PRO (cat. no. 176–9379; RS PRO, Wädenswil, Switzerland).
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4

Synthesis of Fe3O4 Nanoparticles

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PDDA solution (average Mw 400 000–500 000, 20 wt
% in H2O) and TA were purchased from Sigma-Aldrich Inc.
Anhydrous ferric chloride (FeCl3) was purchased from Aladdin
Company (Shanghai, China). Fe3O4 nanoparticles
(NPs) (99.9%, 20 nm in diameter) were purchased from Beijing DK Nano
Technology Co. LTD. Sodium hydroxide (NaOH) and ethanol were purchased
from Sinopharm Chemical Reagent Co. Ltd. All these reagents are used
as received. All aqueous solutions were prepared using Millipore water.
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5

Fabrication of Proton Exchange Membrane

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Zirconium(IV) propoxide solution 70 wt.% in 1-propanol (Zr(OPr n ) 4, Sigma, Japan), ethylene glycol (EG, Sigma, Japan),1-butyl-3-methylimidazolium tetrafluoroborate (BMImBF 4 , Sigma, Japan), absolute ethanol (EtOH, Sigma, Japan), tungsten(VI) chloride (WCl 6 , Sigma, Japan), PVPA solution 30 wt.% (Sigma, Japan), PDDA solution 20 wt.% (Sigma, Japan), N,N-dimethylacetamide (DMAc, Wako, Japan), polybenzimidazole solution 10 wt.% in DMAc, Mw 26000 (PBI, Sato Light Industrial, Japan), phosphoric acid 85% (PA, Wako, Japan), and 0.5 mg cm -2 Pt-loaded carbon paper (Pt/C, Fuel Cell Earth, CTM-GDE-01, USA). All materials and reagents were used as received without further processing.
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6

Cesium Adsorption on Iron-based Nanocomposites

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Materials: Iron (II) chloride tetrahydrate (FeCl2·4H2O), Iron (III) chloride hexahydrate (FeCl3·6H2O), potassium hexacyanoferrate (III) trihydrate (K3[Fe(CN)6]·3H2O), PDDA solution (20 wt %, MW 400,000~500,000), hydrochloric acid (HCl) and ammonium hydroxide (NH4OH), polyvinylpyrrolidone (PVP, MW = 40,000) were purchased from Sigma-Aldrich, Korea. A standard cesium solution (1000 ppm) was purchased from Kanto Chemical Co. Inc. (Tokyo, Japan). All chemicals used in this study were of analytical reagent grade. Deionized (DI) water was used in this study. Additionally, 137Cs solution was provided from the Korea Atomic Energy Research Institute (KAERI), Daejeon, Korea.
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