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2 protocols using 2 ethylhexylamine

1

Lanthanoid Complexes Synthesis and Characterization

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Formaldehyde (36%) was purchased
from VWR; phosphorous acid (99%) and hexylamine (98%) from Fluka Chemical
Co.; 2-ethylhexylamine (98%), La(NO3)3·6H2O, and propylamine hydrochloride from Sigma-Aldrich; ethylamine
hydrochloride (98%), butylamine (99%), and Y(NO3)3·6H2O (99.8%) from Merck; and Lu(NO3)3·H2O from abcr and amylamine (98%) from TCI
chemicals. All of the chemicals were reagent grade and used without
further purification. NMR measurements and titrations were performed
on a Bruker Avance III 300 MHz-spectrometer, and NMR data was processed
with Bruker TopSpin 4.0.8. IR spectra were measured by Bruker Alpha
FT-IR. Elemental analyses were done by an Elementar Vario EL III-analysator.
Lanthanoid concentrations were determined by a Perkin Elmer Optima
8300 DV ICP-OES- spectrometer.
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2

Synthesis of Acrylate and Amine Monomers

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Material Benzylalcohol (≥99%), benzylacrylate (≥99%, contains hydroquinone monomethyl ether (MEHQ) as inhibitor), bisphenol A glycerolate (1 glycerol/phenol) diacrylate (contains 250-500ppm MEHQ as inhibitor), n-butylamine (≥99%), dibutylamine (≥99%), N,Ndiisopropylethylamine (DIPEA, ≥99%) 2-ethylhexylacrylate (98%, contains MEHQ as inhibitor), 2-ethylhexylamine (98%), N-methylbutylamine (≥98%), pentaerythritol triacrylate (PTA, technical grade, contains 600ppm MEHQ as inhibitor), trimethylolpropane triacrylate (TMPTA, technical grade, contains 300-400ppm MEHQ as inhibitor), n-octylamine (99%), were purchased from Sigma-Aldrich. Tetrahydrofuran (THF), and n-hexane were purchased from Acros Organics.
4,4′-methylenebis(cyclohexylamine) (MBCA, >98%) was purchased from TCI. Jeffamine D2000 was kindly provided by Huntsman, and Priamine 1074 was kindly provided by Croda. All reagents were used without further purification unless stated otherwise.
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