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2 protocols using dithioglycerol

1

Synthesis of Metal Chalcogenide Nanostructures

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1-thioglycerol (TGL, 95%) and dithioglycerol (DTG, 95%) were purchased from Sigma Aldrich (Irvine, UK). Lead (II) acetate trihydrate (Pb(CH3COO)2.3H2O, 99.99%), sodium sulfide nonahydrate (Na2S·9H2O, 99.99%), manganese (II) acetate hydrate (Mn(CH3CO2)2·4H2O, 98%), and hydrazine hydrate (N2H4, 80%) were obtained from R&M Chemicals (London, UK). Triethylamine (99.5%) was purchased from Chemiz (Shah Alam, Malaysia) and sodium tellurite (Na2TeO3, 95%) was purchased from Aladdin (Shanghai, China). Deionized water was used throughout the experiments, and all chemicals were used without further purification.
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2

Synthesis of Multifunctional Nanoparticles

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Hydrogen tetrachloroaurate III trihydrate (HAuCl4·3H2O, 99.99%), silver nitrate (AgNO3, 99%), tetraethyl orthosilicate (Si(OC2H5)4, 999.99%), hydroxylamine hydrochloride (NH2O HCl, 94%), sodium citrate (99%), sodium borohydride (NaBH4, 99%), lead (II) acetate trihydrate (99.99%), 1-Thioglycerol (TGL, 95%), dithioglycerol (DTG, 95%), 3-mercaptopropyl trimethoxysilane (MPTMS, 95%), sodium sulfide nonahydrate (Na2S, 99.99), triethylamine ((C2H5)3N, 99%), ammonia hydroxide (NH3, 28–30%), ethanol 200 proof absolute, 3-Aminopropyl triethoxysaline (APTES, 98%), 11-Mercaptoundecanoic acid (MUA, 98%), and absolute ethanol (C2H5OH, 99.5%) where purchased from Sigma Aldrich and used as received. Argon gas (Ar, 99.98%) and nitrogen gas (N, 99.99%) was supplied by Matheson-Trigas. All solutions were prepared using ultrapure water (18 Mohm Millipore Milli-Q water).
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