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3 protocols using zinc acetylacetonate

1

Synthesis of Metal Acetylacetonate Compounds

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Zinc acetylacetonate (Zn(AcAc)2; ≥95.0%), cobalt acetylacetonate (Co(AcAc)2; ≥99.0%), nickel acetylacetonate (Ni(AcAc)2; ≥99.0%), copper acetylacetonate (Cu(A0cAc)2; ≥99.0%), oxalic acid anhydrous (≥99.9%), hexadecyltrimethylammonium bromide (CTAB; ≥99.9%), polyethylene glycol (PEG; 10 000), carbamazepine and ethanol (absolute) were all purchased from Sigma Aldrich and used as provided. Jacketed, fritted funnels were purchased from Chemglass Lifesciences and fitted with PTFE sheets (Zwanzer). Desiccant from a Drierite™ gas-drying unit (Sigma-Aldrich) was used as provided by the manufacturer but transferred to a smaller tube.
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2

Synthesis of Polymer Precursors

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Glycolic acid, dimethyl
terephthalate, adipic acid, succinic acid, bismuth(III) subsalicylate,
antimony(III) oxide, zinc acetylacetonate, zinc acetate, methanesulfonic
acid, phosphoric acid, DMSO-d6, and CDCl3 were purchased from Sigma-Aldrich. 1,4-Butanediol,
tin(II) 2-ethylhexanoate, and titanium butoxide were purchased from
VWR, Alfa Aesar. Zirconium(IV) acetylacetonate was purchased from
Strem Chemicals U.K., Ltd. Irgafos 126, Irgafos 168, and Joncryl ADR
4468 were from BASF.
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3

Synthesis of Nanocomposite Materials

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Pd acetylacetonate (Pd(acac) 2 , 99%), zinc acetylacetonate (Zn(acac) 2 , 99%), aluminium oxide (Al 2 O 3 , nanopowder, <50 nm particle size), gallium oxide (Ga 2 O 3 , 99.99+, %), zinc acetate dihydrate (Zn(CH 3 OH) 2 $6H 2 O, $98%), ammonium carbonate ((NH 4 ) 2 CO 3 , $30% NH 3 basis), and zinc oxide (nanopowder, <100 nm particle size) were supplied by Sigma-Aldrich; aeroxide titanium oxide (TiO 2 , P25) was supplied by Evonik.
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