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2 protocols using copper acetylacetonate

1

Synthesis of Metal Acetylacetonate Compounds

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Zinc acetylacetonate (Zn(AcAc)2; ≥95.0%), cobalt acetylacetonate (Co(AcAc)2; ≥99.0%), nickel acetylacetonate (Ni(AcAc)2; ≥99.0%), copper acetylacetonate (Cu(A0cAc)2; ≥99.0%), oxalic acid anhydrous (≥99.9%), hexadecyltrimethylammonium bromide (CTAB; ≥99.9%), polyethylene glycol (PEG; 10 000), carbamazepine and ethanol (absolute) were all purchased from Sigma Aldrich and used as provided. Jacketed, fritted funnels were purchased from Chemglass Lifesciences and fitted with PTFE sheets (Zwanzer). Desiccant from a Drierite™ gas-drying unit (Sigma-Aldrich) was used as provided by the manufacturer but transferred to a smaller tube.
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2

Synthesis of Copper Nanostructures

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Indium nitrate hydrate
(In(NO3)3·xH2O, 99.9%), copper(I)
acetate (CuOAc, 97%), copper acetylacetonate (Cu(acac)2, 97%), copper(I) iodide (CuI, 98%), copper(I) bromide (CuBr, 98%),
copper(I) chloride (CuCl, 99%), 1-dodecanethiol (1-DDT, ≥98%),
oleic acid (OA, 90%), oleylamine (OLAM, 70%), anhydrous toluene, methanol,
butanol, and ethanol were purchased from Sigma-Aldrich and used as
received.
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