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Pgstat 100 potentiostat

Manufactured by Metrohm
Sourced in Germany

The PGSTAT 100 is a potentiostat, a type of electrochemical measurement instrument. It is designed to apply and measure electrical potential and current between an electrochemical cell's working and reference electrodes. The PGSTAT 100 can be used to perform various electrochemical techniques, including voltammetry and potentiometry.

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2 protocols using pgstat 100 potentiostat

1

Solar Cell Performance Characterization

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Current–voltage measurements were carried out in ambient air under AM 1.5G illumination using a self-calibrating Sinus-70 solar simulator (Wavelabs, Leipzig, Germany). An X200 source meter (Ossila, Sheffield, UK) was used to assess solar cell performance (scan speed 100 mV s−1). A mask was employed to confine the active solar cell area to 0.16 cm2. Ambient light characterization was carried out with a Warm White 930 18 W fluorescent tube (OSRAM, Munich, Germany), and a PGSTAT 100 potentiostat (Metrohm Autolab, Utrecht, The Netherlands) was utilized to record the current–voltage characteristics. The lamp spectrum is illustrated in the ESI, Fig. S6. The stabilized illumination intensity was calibrated with a commercial lux meter (Clas Ohlson, Insjön, Sweden) before measurements. Values of illumination intensity were cross-checked with lux meters from different manufacturers. The entire active photovoltaic area of the devices was used during indoor characterization to mimic diffuse light conditions.
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2

Electrochemical Characterization at Liquid-Liquid Interface

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Cyclic voltammetric experiments were performed using a three-and four-electrode configuration with an Autolab PGSTAT100 potentiostat (Metrohm-Autolab). iR compensation was applied for the electrochemical measurements. Homemade Ag/AgCl reference electrodes (RE) were directly immersed in the chloride-containing aqueous phase, an aqueous solution of 0.1 mM LiCl and 1 mM BTPPACl was brought in contact with the organic solution via a micropipette and formed a liquid junction for the organic reference electrode. The micropipette was prepared from a borosilicate capillary (o.d. 1.5 mm, i.d. 1.1 mm), using a micropipette puller (Sutter P-97 Flaming/Brown). The average internal diameter of the micropipette tip was estimated to be 2-3 µm. The aqueous counter electrode (CE w ) was glass coated to avoid contact of the Pt with the organic (upper) phase (all metals were obtained from Advent Research Materials). The cells used for the liquid/ liquid electrochemical measurements at the organic/water interface, had a working area in the range 0.74-0.83 cm 2 and a total solution volume of 2.5 mL. The errors presented are either standard deviations (arithmetic averages of multiple measured values) or absolute errors determined from the best fit errors.
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