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2 protocols using bromoethane

1

Synthesis and Characterization of Imidazolium-based Ionic Liquids

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Rotiphorese Gel B (MBAA) (2% w/w N,N′-methylenebis(acrylamide), Carl Roth, Karlsruhe, Germany), N,N,N′,N′-tetramethylethylenediamine (TEMED) (≥99.5%; Sigma Aldrich, St. Louis, MO, USA), ammonium persulfate (APS) (98%; Acros Organics, Fair Lawn, NJ, USA), 1-vinylimidazole (≥99%; Alfa Aesar, Haverhill, MA, USA), bromoethane (98%; Alfa Aesar), 1-chlorobutane (≥99%; Acros Organics), 1 bromobutane (99%; Sigma Aldrich), ethanol (EtOH) (≥99.8%), n-heptane (n-Hep) (≥99.5%), and tetrahydrofuran (THF) (≥99.8%) were used in this study. Additionally, ultrapure water was used throughout the study.
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2

Synthesis of Polymerized Acrylamide Compounds

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Acrylamide, polyAcrylamide (average MW 10,000) and trifluoroacetic acid were obtained from Acros Organics (Geel, Antwerp, Belgium). Potassium persulfate, sodium alginate and methacrylic anhydride were purchased from Sigma-Aldrich (St. Louis, MO, USA). N,N′-MethylenebisAcrylamide, 1-vinylimidazole, bromoethane, 1-bromobutane, 1-bromohexane and 1-bromooctane were gained from Alfa Aesar (Ward Hill, MA, USA). Calcium chloride and Boc-Lys-OH were obtained from Merck (Darmstadt, Germany) and Carbosynth (Compton, UK), respectively. Deionized water was used in all the experiments.
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