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4 protocols using 1 3 5 tris 1 phenyl 1h benzimidazol 2 yl benzene tpbi

1

Synthesis of Perovskite Nanocrystals

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Cesium bromide (CsBr, 99.999%), lead bromide (PbBr2, 99.999%), oleic acid (OA, 90%), dimethyl sulfoxide (DMSO, 99.5%), chlorobenzene (CB, 99.5%), and polyethyleneimine (PEI) were obtained from Sigma-Aldrich. Oleylamine (OLA, 80-90%), methyl acetate (99%), and N-butanol (99.8%) were obtained from Aladdin. Hydrobromic acid (40 wt% in H2O) was purchased from Tianjin Chemical Industry. 4-Dodecylbenzene sulfonic acid (DBSA, 95%) was purchased from Shanghai Acmec Biochemical Co., Ltd. Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), poly(4-butylphenyl-diphenyl-amine) (Poly-TPD), 1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)benzene (TPBi), and 2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine (POT2T) were purchased from Xi’an Polymer Light Technology Corp. Hexane, ethanol, dichloromethane, isopropyl alcohol, toluene, and acetone were obtained from Sinopharm Chemical Reagent Co., Ltd.
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2

Fabrication of OLEDs on ITO Substrates

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Indium tin oxide (ITO) substrates (thickness of 185 nm, sheet resistance ≤ 6 Ω, transmittance ≥ 84%) were purchased from South China Science & Technology Company, Shenzhen. PEDOT:PSS (4083), CBP (purity > 99%), 1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)benzene (TPBI, purity > 99%) and lithium fluoride (LiF) were obtained from Xi'an Polymer Light Technology Company. All solvents were purchased from J&K Scientific, Ltd (China) unless otherwise indicated. All chemicals were used without further purification.
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3

Optimizing Perovskite Solar Cell Fabrication

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All chemicals were used without further purification. Phthalic (PA, 99.5%) and citric acid (CA, 99.5%) were purchased from Aladdin. Ethylenediamine (EDA, 99%) and cesium bromide (CsBr, 99.999%) were purchased from Alfa Aesar. Poly(ethylene oxide) (PEO, average Mv 100,000), lithium fluoride (LiF, 99.98%), n-butylammonium bromide (BABr, 98%), and dimethyl sulfoxide (DMSO, ≥ 99.9%) were purchased from Sigma Aldrich. Lead bromide (PbBr2 98%) was purchased from TCI. Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) (4083) and 1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene (TPBi, 99.5%) were purchased from Xi’an Polymer Light Technology Corp.
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4

Organic Semiconductor Material Synthesis

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10-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-10H-spiro [acridine-9,9’-fluorene] (SpiroAC-TRZ) and 3,3’-Di(9H-carbazol-9-yl) biphenyl(m-CBP) were purchased from Taiwan Luminescence Technology Corp.
Dipyrazino[2,3-f:2’,3’-h ]quinoxaline-2,3,6,7,10,11-hexacarbonitrile (HAT-CN), di-[4-(N,N -di-p -tolyl-amino)-phenyl]cyclohexane (TAPC) and 1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)benzene (TPBi) were purchased from Xi’an Polymer Light Technology Corp.
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