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2 protocols using calcium 2 nitrate tetrahydrate

1

Synthesis and Characterization of ZIF-8/ZIOS

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Zinc(II) nitrate hexahydrate (≥98%), 2-methylimidazole (>99%), salicylaldoxime, copper(II) chloride dehydrate, calcium(II) nitrate tetrahydrate, iron(II) chloride tetrahydrate, iron(III) chloride, nickel(II) nitrate hexahydrate, manganese(II) chloride, and sodium chloride were purchased from Sigma-Aldrich and used as received. Anhydrous methanol (>99.8%, Sigma-Aldrich) and Milli-Q water (18.2 MΩ cm−1) were used in the synthesis of ZIF-8/ZIOS and ion solution preparations, respectively.
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2

Metal-Organic Framework for Diclofenac Removal

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Copper(II) nitrate trihydrate (Cu(NO3)2·3H2O), silver(I) nitrate (AgNO3), calcium(II) nitrate tetrahydrate (Ca(NO3)2·4H2O), cobalt(II) nitrate hexahydrate (Co(NO3)2·6H2O), manganese(II) nitrate tetrahydrate (Mn(NO3)2·4H2O), zinc(II) nitrate hexahydrate (Zn(NO3)2·6H2O), benzene-1,3,5-tricarboxylic acid (H3BTC), and methylene blue (MB) were purchased from Sigma Aldrich, Taufkirchen, Germany. N,N-dimethyl formamide (DMF) was procured from Samchun Pure Chemicals, Pyeongtaek-si Korea. Diclofenac sodium salt (DCF, C14H10Cl2NNaO2) was procured from TCI Chemicals, Tokyo, Japan. Pure H2S (500 ppm) balanced with N2 gas was procured from Union gas, Seoul, Korea.
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