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3 protocols using na2co3

1

Heterogeneous Catalysts for Hydrogenation

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MgCl2·6H2O (98.0 %), AlCl3·6H2O (97.0 %) and cyclohexane (99.5 %) were purchased from Shanghai Macklin Biochemical Co., ltd. NaOH (96.0 %) and Na2CO3 (99.8 %) were provided by Tianjin Guangfu Technology Development Co., ltd. Carboxyl-functionalized CNT (diameter 20–30 nm, length 0.5–2 μm) was manufactured by Nanjing Xianfeng Nanomaterials Technology Co., ltd. RuCl3·3H2O and NEC (98 %) were produced by Zhejiang Metallurgical Research Institute Co., ltd. and Beijing Coupling Technology Co., ltd., respectively. H2 (99.999 %) and N2 (99.999 %) were purchased from Harbin Qinghua Industrial Gas Co., ltd. Commercial Ru/Al2O3 (5 wt%) catalyst was produced at Alfa Aesar Chemical Co., ltd.
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2

Sponge-Supported Catalysts Synthesis

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Materials: Sponge (polyurethane, 5 mm thickness) was produced by Nanjing Saneduo Sponge (Nanjing, China); CuSO4 5H2O (99 wt%) and HCl (37.5 wt%) were purchased from Beijing Chemical Works (Beijing, China); NaKC4H4O6 (99 wt%), Na3PO4·12H2O (98 wt%), SDBS (90 wt%), and Na2CO3 (99.8 wt%) were from Tianjin Guangfu Technology Development Co., Ltd. (Tianjin, China); NaOH (96 wt%) was from Tianjin Beichen Founder Reagent Factory (Tianjin, China; NiCl2·6H2O (98 wt%) and SnCl2·2H2O (98 wt%) were from Tianjin Yongsheng Fine Chemicals Co., Ltd. (Tianjin, China); HCHO (36 wt%) was from Liaoning Quan Rui Reagent Co., Ltd. (Liaoning, China); Op-10 emulsifier (99 wt%) was from Tianjin Zhiyuan Chemical Reagent Co., Ltd. (Tianjin, China); and PdCl2 (99.9 wt%) was from Tianjin Chemical Reagent Third Factory (Tianjin, China).
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3

Synthesis and Characterization of Gold Nanoparticles

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Hydrogen tetrachloroaurate trihydrate (HAuCl4·3H2O), folic acid (FA), 11-mercaptoundecanoic acid (MUA) and trichloroacetic acid were obtained from Aladdin Reagent Co., Ltd. (Shanghai, China). Bovine serum albumin (BSA, fraction V) and amino acids (Ile, Pro, Arg, Gly, Gln, Ser, Ala, Leu, His) were purchased from Beijing Dingguo Changsheng Biotech Co. (Beijing, China). Other routine reagents like HCl, NaOH, NaCl, KCl, MgCl2, CaCl2, Na2CO3, NaHCO3, NaH2PO4, Na2HPO4 and Na3PO4 were purchased from Tianjin Guangfu Fine Chemical Research Institute (Tianjin, China). All chemicals were of analytical reagent grade and were used without further purification. The water used throughout all the experiments was purified through a Millipore system.
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