Dmf d7

The triblock terpolymers were analyzed by proton nuclear magnetic resonance spectroscopy (¹H-NMR). ¹H-NMR measurements were performed on a Bruker Ascend 500 NMR spectrometer (500 MHz) (Bruker BioSpin GmbH, Rheinstetten, Germany) using CDCl₃ (Sigma-Aldrich, Schnelldorf, Germany) and DMF-d7 (Sigma-Aldrich, Schnelldorf, Germany) as solvent at room temperature.

Silicone polyol (DMS-C15) was purchased from Gelest, USA. IPDI, DMF, glycerol 1,2-carbonate, and furfurylamine were purchased from Tokyo Chemical Industry, Japan. DMF-d7, dibutyltin dilaurate, and BMI were purchased from Sigma-Aldrich, USA. All chemicals were used as received without purification. An AgNW solution dispersed in IPA was purchased from Dittotechnology Ltd., Korea. The average diameter and length of the nanowires were 35 nm and 20 μm, respectively.

All reactions were carried out under a dry, argon atmosphere using a standard Schlenk line or glove box techniques. Solvents were purified as appropriate: en (Aldrich, 99.8%) was refluxed over CaH₂ for 24 hours, distilled and stored on 4 Å molecular sieves; DMF (Aldrich, 99.8%) and DMF-d₇ (Sigma-Aldrich, 99.5%) were stored over 3 Å molecular sieves for five days, distilled under vacuum (~50 mbar) and stored on 4 Å molecular sieves; acetonitrile (VWR Chemicals, >99%) was stored over 3 Å molecular sieves for five days, distilled and stored on 3 Å molecular sieves; and n-hexane (Sigma-Aldrich, >95%) and toluene (Acros Organics) were refluxed over Na for 24 hours, distilled and stored on 4 Å molecular sieves. The crypt-222 (Kryptofix 222, Sigma-Aldrich) was dried under vacuum. The A was prepared by the published procedure on a larger scale (0.50 mmol)^{44 (link)}. All other reagents were used as received: K (Acros Organics, 98%), Bi powder (ChemPur, 99.5%), [(cod)IrCl]₂ (ChemPur) and [CpRu(MeCN)₃][PF₆] (Sigma-Aldrich). K₅Bi₄ was synthesized by combining K and Bi in stoichiometric amounts in a niobium ampoule. The ampoule was sealed by arc-welding, sealed in a quartz tube under vacuum, placed in an oven and kept at 700 °C for 7 days.

BiCl₃, BiBr₃, BiI₃, and hydrazine hydrate were obtained from Sigma-Aldrich.
DMF-d₇ was purchased from Sigma-Aldrich.
All other reagents were purchased from Fluorochem and Apollo Scientific
and used without further purification. HPLC-grade dimethylformamide
(DMF), acetonitrile (ACN), and tetrahydrofuran (THF) were purchased
from Sigma-Aldrich for photophysical analysis.

The chemicals K₂[PtCl₄] was purchased from Precious Metals Online, while KI, 7-azaindole, 3-chloro-7-azaindole, 3-bromo-7-azaindole, 3-iodo-7-azaindole, 4-chloro-7-azaindole, 4-bromo-7-azaindole, 5-bromo-7-azaindole, 4-chloro-2-methyl-7-azaindole, cisplatin, oxaliplatin, reduced glutathione, guanosine 5′-monophosphate disodium salt hydrate, ethidium bromide, tris(hydroxymethyl)aminomethane, calf thymus DNA, Roswell Park Memorial Institute medium, fetal calf serum, glutamine, penicillin and streptomycin, and solvents (methanol, diethyl ether, n-octanol, DMF-d₇, D₂O) were supplied by Sigma-Aldrich Co. and Fisher-Scientific Co.